Citation: Zhanglin Shi, Tao Xiu, Xinmeng Mao, Jianfeng Wu, Baoliang Zhang. TCF/Co@NC复合纳米纤维的可控制备及其微波吸收性能[J]. Acta Physico-Chimica Sinica, ;2026, 42(11): 100306. doi: 10.1016/j.actphy.2026.100306 shu

TCF/Co@NC复合纳米纤维的可控制备及其微波吸收性能

Zhanglin Shi ¹ ,
Tao Xiu ¹ ,
Xinmeng Mao ^1,2 ,
Jianfeng Wu ¹ ,
Baoliang Zhang ^1,3,,

1.
School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072, Shaanxi Province, China;
2.
Xi'an Key Laboratory of Functional Organic Porous Materials, Northwestern Polytechnical University, Xi'an 710072, Shaanxi Province, China;
3.
Shaanxi Engineering and Research Center for Functional Polymers on Adsorption and Separation, Sunresins New Materials Co. Ltd., Xi'an 710076, Shaanxi Province, China

Corresponding author: Baoliang Zhang, blzhang@nwpu.edu.cn
Received Date: 12 March 2026
Revised Date: 14 April 2026
Accepted Date: 16 April 2026

将磁性纳米颗粒复合到一维(1D)多孔碳基质上具有重要研究价值。该策略对于制备高效且功能协同的微波吸收体至关重要。本工作通过超交联聚合从管状多孔纤维衍生出一维碳材料，以此为前驱体构建了一系列涂覆Co/Zn金属有机框架(MOFs)的复合纤维(C-CCNFs@Co/Zn-MOFs)。优化了包覆工艺，揭示了Zn²⁺离子对MOF晶粒尺寸的调控机制。后续碳化处理获得磁性氮掺杂碳包覆钴/管状碳纳米纤维(TCF/Co@NC)。该TCF/Co@NC具有多孔核壳结构和一维形貌，富含异质界面。这些特性有利于构建导电损耗网络并产生多重反射，形成强能量耗散能力。通过调节Co/Zn摩尔比，可优化复合纤维的电磁参数，从而调控其微波吸收性能。所制备的NCT-3 (Co/Zn=1 : 1)在2.7 mm厚度处获得-55.5 dB的最小反射损耗(RL_min)；而NCT-2 (Co/Zn=3 : 1)在2.4 mm厚度下展现出7.3 GHz的有效吸收带宽(EAB)。本研究为设计高性能磁性碳基微波吸收材料提供了普适且可借鉴的方法论。
- Hyper-cross-linked polymers,
- Tubular fibers,
- Metal-organic frameworks (MOFs),
- Magnetic materials,
- Microwave absorbers
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