Citation: Zhimin Sun, Wenyu Xue, Shuangshuang Yang, Chaoyang Zhang, Bo Yu, Xingwei Wang, Qiangliang Yu, Feng Zhou, Weimin Liu. 面向海洋应用的多功能涂层：基于氟硅烷包覆CIP实现防腐、吸波与减阻一体化[J]. Acta Physico-Chimica Sinica, ;2026, 42(11): 100292. doi: 10.1016/j.actphy.2026.100292 shu

面向海洋应用的多功能涂层：基于氟硅烷包覆CIP实现防腐、吸波与减阻一体化

Zhimin Sun ^1,2 ,
Wenyu Xue ^1,2 ,
Shuangshuang Yang ^1,2 ,
Chaoyang Zhang ^1,2 ,
Bo Yu ¹ ,
Xingwei Wang ^1,2,, ,
Qiangliang Yu ^1,2,, ,
Feng Zhou ¹ ,
Weimin Liu ^1,2

1.
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu Province, China;
2.
Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai, Yantai 264000, Shandong Province, China

Corresponding author: Xingwei Wang, Qiangliang Yu,
Received Date: 11 February 2026
Revised Date: 22 March 2026
Accepted Date: 24 March 2026

羰基铁粉(CIP)是一种典型的磁损耗型微波吸收材料。然而，其在严苛海洋环境(高湿度、高盐度)下易发生电化学腐蚀，导致性能退化，限制了长期应用。本研究通过溶胶-凝胶法将全氟癸基三甲氧基硅烷(PFOTES)包覆在CIP表面制备了核壳结构粒子(CIP@PFOTES)。随后将粒子掺入氟硅树脂(FSR-ZY220L)中，制得多功能CIP@PFOTES-ZY涂层。该涂层表现出超疏水性，水接触角达158°。在0.1-100 s^-1剪切速率范围内减阻率超过70%。中性盐雾环境中涂层展现出优异的长期耐腐蚀性能，电化学阻抗谱(EIS)表明在3.5 wt.% NaCl溶液中浸泡40 d后，低频阻抗模值(|Z|_0.01 Hz)仍保持在10⁷ Ω cm²以上。此外，1.3 mm厚度涂层获得7.52 GHz有效吸收带宽(EAB，RL ≤ -10 dB)，微波吸收性能较未改性样品显著提升。本研究为开发适用于严苛海洋环境的高性能、多功能防护涂层提供了一种有效的材料设计策略。
- Carbonyl iron powder,
- Core-shell structure,
- Corrosion resistance,
- Microwave absorption,
- Drag reduction,
- Superhydrophobicity
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沈阳化工大学材料科学与工程学院沈阳 110142