Citation: Yunhan Gao,  Xing Sun,  Mengxia Ji,  Xingchang Qiu,  Tiange Wei,  Qing Xu,  Sheng Yin,  Jiexiang Xia,  Huaming Li. Hierarchical ZIF-derived carbon/Bi12O17Cl2 heterostructures synergistically enhance electron dynamics and optical properties to boost CO2 photoreduction in pure water[J]. Acta Physico-Chimica Sinica, ;2026, 42(10): 100264. doi: 10.1016/j.actphy.2026.100264 shu

Hierarchical ZIF-derived carbon/Bi12O17Cl2 heterostructures synergistically enhance electron dynamics and optical properties to boost CO2 photoreduction in pure water

  • Corresponding author: Mengxia Ji,  Jiexiang Xia,  Huaming Li, 
  • Received Date: 3 December 2025
    Revised Date: 16 February 2026
    Accepted Date: 25 February 2026

  • Conventional Bi12O17Cl2 photocatalyst suffer from narrow solar harvesting, weak CO2 adsorption and poor charge utilization. Herein, an intimate hierarchical heterojunction was constructed by embedding Bi12O17Cl2 ultrathin nanotubes into hierarchical Co-ZIF-derived porous carbon (Co-PC/BOC). Multi-cavity reflection within Co-PC nanocages and localized surface plasmon resonance of in situ generated Co3O4 domains synergistically enhance the light harvest ability of the Co-PC/BOC in the full spectral range. In pure water without any photosensitizers or sacrificial agents, the optimal composite exhibits a CO yield of 34.16 μmol g-1 h-1 with 100% selectivity, 2.9-fold higher than bare BOC. In situ DRIFTS and photo/electrochemical characterizations demonstrate that Co-PC serves as a dual-function platform of plasmonic hot-electron injector and charge separation hub, whereas BOC provide abundant surface sites for *COOH formation and *CO cleavage. Our work highlights the promising potential of metal-organic frameworks and their derivatives in developing efficient artificial photosynthesis systems.
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