Citation: Lishan Chen, Xuemei Li, Xiangju Xu, Youqing Dong, Quanlong Xu. MA3Bi2Br9/g-C3N4 0D/2D S-scheme heterojunction for selective photooxidation of toluene[J]. Acta Physico-Chimica Sinica, ;2026, 42(9): 100258. doi: 10.1016/j.actphy.2026.100258 shu

MA3Bi2Br9/g-C3N4 0D/2D S-scheme heterojunction for selective photooxidation of toluene

  • Corresponding author: Youqing Dong, yqdong@wzu.edu.cn Quanlong Xu, xuql@wzu.edu.cn
  • Received Date: 23 January 2026
    Revised Date: 9 February 2026
    Accepted Date: 10 February 2026

  • Toluene to high-value benzaldehyde conversion remains a great challenge due to the reactive inertness of sp3 C–H bonds. Herein, MA3Bi2Br9/g-C3N4 heterojunction was precisely fabricated by employing an in situ growth approach, and O2 molecule was used as the green oxidant. Band structure analysis and advanced characterizations demonstrate the S-scheme mechanism working on the MA3Bi2Br9/g-C3N4 heterojunction, thus enabling the powerful photogenerated electron/holes pairs and large driven force for generating ·O2 species, a critical reactive oxygen species in selective oxidation of toluene. The optimized 20%MA3Bi2Br9/g-C3N4 displays enhanced toluene conversion and product selectivity, reaching 27.4% conversion and 94.2% benzaldehyde selectivity within 4 h. This study provides a universal strategy for future exploration of novel heterojunctions capable of high photocatalytic performance in converting hydrocarbons to high-value chemicals.
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