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Citation: Vanita Vanita,  Roland Schoch,  Pascal Puphal,  Hasan Yilmaz,  Matthias Bauer,  Oliver Clemens. Structural and electrochemical behaviour of bilayer manganite LaSr2Mn2O6.96 cathode for all-solid-state fluoride ion batteries[J]. Acta Physico-Chimica Sinica, ;2026, 42(3): 100181. doi: 10.1016/j.actphy.2025.100181 shu

Structural and electrochemical behaviour of bilayer manganite LaSr2Mn2O6.96 cathode for all-solid-state fluoride ion batteries

  • 1.

    University of Stuttgart, Institute for Materials Science, Materials Synthesis Group, Heisenbergstraße 3, 70569 Germany;

  • 2.

    Institute of Inorganic Chemistry and Center for Sustainable Systems Design (CSSD), Paderborn University, Warburger Straße 100, 33098 Paderborn, Germany;

  • 3.

    Max-Planck-Institute, Heisenbergstr. 1, 70569 Stuttgart, Germany

  • In this study, we explore the potential of the Ruddlesden-Popper (RP)-type bilayer manganite LaSr2Mn2O6.96 as an intercalation-based cathode material for all-solid-state fluoride ion batteries (FIBs). Structural changes of LaSr2Mn2O6.96 during fluoride intercalation and de-intercalation were analyzed via ex situ X-ray diffraction, revealing that F- insertion induces the formation of three distinct tetragonal phases. To understand the complex behavior of these phases, we examined the changes in the Mn oxidation state and coordination environment using X-ray absorption spectroscopy and magnetic measurements. Under stack pressure (20 kN), electrochemical cycling of LaSr2Mn2O6.96 in the potential range of 1 V to -1 V exhibited a continuous increase in specific capacity from capacity of ~30 mAh g-1 to ~68 mAh g-1 over 200 cycles, with ~99% coulombic efficiency and no signs of capacity fading. This makes the bilayer manganite LaSr2Mn2O6.96 a promising candidate for a cycling stable cathode for all-solid-state FIBs, especially under the application of stack pressure.
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