Citation: Ziyi Xiao, Xinyi Ma, Linping Wang, Haobin Hu, Enzhou Liu. Efficient photocatalytic conversion H₂S over NiS₂/twinned-Mn_0.5Cd_0.5S Schottky/S-scheme homojunction in Na₂S/Na₂SO₃ solution[J]. Acta Physico-Chimica Sinica, ;2026, 42(4): 100171. doi: 10.1016/j.actphy.2025.100171 shu

Efficient photocatalytic conversion H₂S over NiS₂/twinned-Mn_0.5Cd_0.5S Schottky/S-scheme homojunction in Na₂S/Na₂SO₃ solution

Ziyi Xiao ¹ ,
Xinyi Ma ¹ ,
Linping Wang ² ,
Haobin Hu ^3,, ,
Enzhou Liu ^1,,

1.
School of Chemical Engineering/Xi'an Key Laboratory of Special Energy Materials, Northwest University, Xi'an 710069, Shaanxi Province, China
2.
PetroChina Changqing Oilfield Company Oil and Gas Technology Research Institute, Xi'an 710021, Shaanxi Province, China
3.
Gansu Key Laboratory of Efficient Utilization of Oil and Gas Resources in Longdong, Longdong University, Qingyang 745000, Gansu Province, China

Corresponding author: Haobin Hu, hhb-88@126.com Enzhou Liu, liuenzhou@nwu.edu.cn
Received Date: 26 July 2025
Revised Date: 19 August 2025
Accepted Date: 20 August 2025

The concurrent production of hydrogen (H₂) and high-value products from waste and toxic hydrogen sulfide (H₂S) has long been a goal in the field of photocatalytic decomposition of H₂S. In this study, the twinned Mn_0.5Cd_0.5S (T-MCS) was selected for its combination of solid solution and twin structure advantages, significantly promoting the bulk phase separation of CdS-based photocatalysts. Furthermore, the highly conductive nickel disulfide (NiS₂) was loaded onto T-MCS to create a NiS₂/T-MCS composite photocatalyst that features both a bulk phase S-scheme homojunction and an interface Schottky junction. NiS₂ not only introduces a large number of active sites, but also improves the separation of surface charges obviously. Utilizing a 0.1 mol L⁻¹ (M) sodium sulfide (Na₂S) and 0.6 M anhydrous sodium sulfite (Na₂SO₃) solution saturated with H₂S as the reaction solution, the 8 wt% NiS₂/T-MCS composite achieves a remarkable hydrogen production rate of up to 59.95 mmol h⁻¹ g⁻¹. Fourier Transform Infrared (FTIR) spectroscopy and Ultraviolet-Visible (UV-Vis) spectroscopy confirm that the sulfur compounds in the reaction solution are nearly completely converted into high-value sodium thiosulfate (Na₂S₂O₃). The S₂O₃²⁻ was also quantitatively determined by titration. This work presents a novel solid solution twin crystal-based homojunction and Schottky junction for both the photocatalytic treatment of H₂S and the production of Na₂S₂O₃.
- H₂S treatment,
- Twinned Mn_0.5Cd_0.5S,
- NiS₂,
- Homo-heterojunction,
- Photocatalysis
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Efficient photocatalytic conversion H2S over NiS2/twinned-Mn0.5Cd0.5S Schottky/S-scheme homojunction in Na2S/Na2SO3 solution

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通讯作者: 陈斌, bchen63@163.com

Efficient photocatalytic conversion H₂S over NiS₂/twinned-Mn_0.5Cd_0.5S Schottky/S-scheme homojunction in Na₂S/Na₂SO₃ solution