Citation: Chunhui Gao, Lurong Li, Guanwei Peng, Jinni Shen, Wenxin Dai, Zizhong Zhang. Efficient photocatalytic NADH regeneration and enzymatic CO₂ reduction over[Cp^*Rh(bpy)H₂O]²⁺ self-assembled CdIn₂S₄ flower-like microspheres[J]. Acta Physico-Chimica Sinica, ;2026, 42(3): 100165. doi: 10.1016/j.actphy.2025.100165 shu

Efficient photocatalytic NADH regeneration and enzymatic CO₂ reduction over[Cp^*Rh(bpy)H₂O]²⁺ self-assembled CdIn₂S₄ flower-like microspheres

Chunhui Gao ^{1, 2} ,
Lurong Li ² ,
Guanwei Peng ² ,
Jinni Shen ² ,
Wenxin Dai ^{1, 2, 3} ,
Zizhong Zhang ^{1, 2,,}

1.
College of Chemical Engineering, Fuzhou University, Fuzhou 350116, Fujian Province, China
2.
State Key Laboratory of Chemistry for NBC Hazards Protection, College of Chemistry, Fuzhou University, Fuzhou 350116, Fujian Province, China
3.
Qingyuan Innovation Laboratory, Quanzhou 362801, Fujian Province, China

Corresponding author: Zizhong Zhang, z.zhang@fzu.edu.cn
Received Date: 15 July 2025
Revised Date: 14 August 2025
Accepted Date: 17 August 2025

Integrating photocatalytic cofactor regeneration with enzymatic cascades enables sustainable CO₂ valorization but faces challenges like limited hydrogen sources and homogeneous mediator and photogenerated holes-induced enzyme deactivation. This study demonstrates that the low oxidation potential of L-ascorbic acid (L-AA) can enhance proton supply and promote the formation of[Cp^*Rh(bpy)H]⁺ intermediates. Only 0.26 mg (≈ 0.12 mmol L⁻¹)[Cp^*Rh(bpy)Cl]Cl can achieve efficient/selective reduced nicotinamide adenine dinucleotide (NADH) regeneration, which is more than twice as effective as the typical sacrificial agent triethanolamine (TEOA). A novel strategy was developed via electrostatic self-assembly of [Cp^*Rh(bpy)H₂O]²⁺ onto CdIn₂S₄ microsphere photocatalysts. This innovative integration physically separated free mediators and photogenerated holes from enzymes, effectively suppressing enzyme deactivation through spatial compartmentalization. The optimal integrated photocatalytic system achieved 90% NADH regeneration efficiency within 40 min of 420 nm light irradiation, outperforming previously reported systems. When coupled with formate dehydrogenase (FDH), the integrated system achieved formic acid generation rates of 443.5 μmol g⁻¹ h⁻¹ (one light-dark cycle) and 202.7 μmol g⁻¹ h⁻¹ (continuous light), representing 1.2- and 3.2-fold improvements over free mediator systems, respectively. This study provides an efficient and sustainable new strategy for light driven coenzyme regeneration and enzyme catalyzed CO₂ synthesis of high value-added chemicals.
- Photoenzyme-coupled catalysis,
- CdIn₂S₄ microspheres,
- CO₂ conversion,
- Electronic mediator integration,
- NADH regeneration
1. [1]
  M. Meinshausen, N. Meinshausen, W. Hare, S.C.B. Raper, K. Frieler, R. Knutti, D.J. Frame, M.R. Allen, Nature 458 (2009) 1158, https://doi.org/10.1038/nature08017. doi: 10.1038/nature08017
2. [2]
  R. Chen, Q. Wu, J. Luo, X. Zu, S. Zhu, Y. Sun, Acta Phys. Chim. Sin. 41 (2025) 100019, https://doi.org/10.3866/PKU.WHXB202308052. doi: 10.3866/PKU.WHXB202308052
3. [3]
  X. Chang, T. Wang, J. Gong, Energy Environ. Sci. 9 (2016) 2177, https://doi.org/10.1039/C6EE00383D. doi: 10.1039/C6EE00383D
4. [4]
  C. Zhuang, W. Li, Y. Chang, S. Li, Y. Zhang, Y. Li, J. Gao, G. Chen, Z. Kang, J. Mater. Chem. A 12 (2024) 5711, https://doi.org/10.1039/d3ta07951a. doi: 10.1039/d3ta07951a
5. [5]
  J. Zhang, G. Yu, C. Yang, S. Li, Curr. Opin. Chem. Eng. 45 (2024) 101040, https://doi.org/10.1016/j.coche.2024.101040. doi: 10.1016/j.coche.2024.101040
6. [6]
  K. Dong, C. Shen, R. Yan, Y. Liu, C. Zhuang, S. Li, Acta Phys. Chim. Sin. 40 (2024) 2310013, https://doi.org/10.3866/PKU.WHXB202310013. doi: 10.3866/PKU.WHXB202310013
7. [7]
  C. Wang, C. You, K. Rong, C. Shen, F. Yang, S. Li, Acta Phys. Chim. Sin. 40 (2024) 2307045, https://doi.org/10.3866/PKU.WHXB202307045. doi: 10.3866/PKU.WHXB202307045
8. [8]
  D. Feng, X. Li, Y. Liu, X. Chen, S. Li, Renewables 1 (2023) 485, https://doi.org/10.31635/renewables.023.202300037. doi: 10.31635/renewables.023.202300037
9. [9]
  S. Li, C. You, K. Rong, C. Zhuang, X. Chen, B. Zhang, Adv. Powder Mater. 3 (2024) 100183, https://doi.org/10.1016/j.apmate.2024.100183. doi: 10.1016/j.apmate.2024.100183
10. [10]
  M. Cai, Y. Liu, K. Dong, X. Chen, S. Li, Chin. J. Catal. 52 (2023) 239, https://doi.org/10.1016/s1872-2067(23)64496-1. doi: 10.1016/s1872-2067(23)64496-1
11. [11]
  Y. Kong, W. Wei, L. Xu, C. Chen, Acta Phys. Chim. Sin. 40 (2024) 2307049, https://doi.org/10.3866/PKU.WHXB202307049. doi: 10.3866/PKU.WHXB202307049
12. [12]
  M. Lin, M. Luo, Y. Liu, J. Shen, J. Long, Z. Zhang, Chin. J. Catal. 50 (2023) 239, https://doi.org/10.1016/S1872-2067(23)64477-8. doi: 10.1016/S1872-2067(23)64477-8
13. [13]
  H.-R. Zhu, H.-M. Xu, C.-J. Huang, Z.-J. Zhang, Q.-N. Zhan, T.-Y. Shuai, G.-R. Li, Chin. J. Catal. 62 (2024) 53, https://doi.org/10.1016/S1872-2067(24)60053-7. doi: 10.1016/S1872-2067(24)60053-7
14. [14]
  C. Fu, Z. Wan, X. Yang, J. Zhang, Z. Zhang, J. Mater. Chem. A 12 (2024) 28618, https://doi.org/10.1039/D4TA04600E. doi: 10.1039/D4TA04600E
15. [15]
  H. Xu, Z. Wang, H. Liao, D. Li, J. Shen, J. Long, W. Dai, X. Wang, Z. Zhang, Appl. Catal. B Environ. 336 (2023) 122935, https://doi.org/10.1016/j.apcatb.2023.122935. doi: 10.1016/j.apcatb.2023.122935
16. [16]
  S.H. Lee, D.S. Choi, S.K. Kuk, C.B. Park, Angew. Chem. Int. Ed. 57 (2018) 7958, https://doi.org/10.1002/anie.201710070. doi: 10.1002/anie.201710070
17. [17]
  X. Tan, J. Nielsen, Chem. Soc. Rev. 51 (2022) 4763, https://doi.org/10.1039/D2CS00309K. doi: 10.1039/D2CS00309K
18. [18]
  S. Zhang, S. Liu, Y. Sun, S. Li, J. Shi, Z. Jiang, Chem. Soc. Rev. 50 (2021) 13449, https://doi.org/10.1039/D1CS00392E. doi: 10.1039/D1CS00392E
19. [19]
  S. Li, J. Shi, S. Liu, W. Li, Y. Chen, H. Shan, Y. Cheng, H. Wu, Z. Jiang, Chin. J. Catal. 44 (2023) 96, https://doi.org/10.1016/S1872-2067(22)64154-8. doi: 10.1016/S1872-2067(22)64154-8
20. [20]
  Y. Sun, J. Shi, Z. Wang, H. Wang, S. Zhang, Y. Wu, H. Wang, S. Li, Z. Jiang, J. Am. Chem. Soc. 144 (2022) 4168, https://doi.org/10.1021/jacs.1c12790. doi: 10.1021/jacs.1c12790
21. [21]
  F. Hollmann, D.J. Opperman, C.E. Paul, Angew. Chem. Int. Ed. 60 (2021) 5644, https://doi.org/10.1002/anie.202001876. doi: 10.1002/anie.202001876
22. [22]
  Y. Cui, J. Zhang, H. Chu, L. Sun, K. Dai, Acta Phys. Chim. Sin. 40 (2024) 2405016, https://doi.org/10.3866/pku.Whxb202405016. doi: 10.3866/pku.Whxb202405016
23. [23]
  P. Li, Y. Cui, Z. Wang, G. Dawson, C. Shao, K. Dai, Acta Phys. Chim. Sin. 41 (2025) 100065, https://doi.org/10.1016/j.actphy.2025.100065. doi: 10.1016/j.actphy.2025.100065
24. [24]
  Y. Liu, C. Chen, G. Dawson, J. Zhang, C. Shao, K. Dai, J. Mater. Sci. Technol. 233 (2025) 10, https://doi.org/10.1016/j.jmst.2024.12.094. doi: 10.1016/j.jmst.2024.12.094
25. [25]
  G. Zhao, C. Yang, W. Meng, X. Huang, J. Mater. Chem. A 12 (2024) 3209, https://doi.org/10.1039/D3TA07015H. doi: 10.1039/D3TA07015H
26. [26]
  H. Wu, C. Tian, X. Song, C. Liu, D. Yang, Z. Jiang, Green Chem. 15 (2013) 1773, https://doi.org/10.1039/C3GC37129H. doi: 10.1039/C3GC37129H
27. [27]
  L. Tong, Z. Gong, Y. Wang, J. Luo, S. Huang, R. Gao, G. Chen, G. Ouyang, J. Am. Chem. Soc. 146 (2024) 21025, https://doi.org/10.1021/jacs.4c06142. doi: 10.1021/jacs.4c06142
28. [28]
  H. Guo, L. Luan, J. Cai, X. Ji, H. Yu, Y. Huang, Chem. Eng. J. 479 (2024) 147720, https://doi.org/10.1016/j.cej.2023.147720. doi: 10.1016/j.cej.2023.147720
29. [29]
  S. Wang, X. Wu, J. Fang, F. Zhang, Y. Liu, H. Liu, Y. He, M. Luo, R. Li, ACS Catal. 13 (2023) 4433, https://doi.org/10.1021/acscatal.2c05722. doi: 10.1021/acscatal.2c05722
30. [30]
  H. Zhao, L. Wang, G. Liu, Y. Liu, S. Zhang, L. Wang, X. Zheng, L. Zhou, J. Gao, J. Shi, Y. Jiang, ACS Catal. 13 (2023) 6619, https://doi.org/10.1021/acscatal.2c06332. doi: 10.1021/acscatal.2c06332
31. [31]
  P. Wei, Y. Zhang, J. Dong, Y. Cao, S.M.Y. Lee, W. Lou, C. Peng, Appl. Catal. B Environ. Energy. 357 (2024) 124257, https://doi.org/10.1016/j.apcatb.2024.124257. doi: 10.1016/j.apcatb.2024.124257
32. [32]
  S. Liu, J. Shi, J. Jia, Y. Yang, S. Zhang, D. Yang, Y. Chen, S. Li, Z. Jiang, ACS Catal. 13 (2023) 14233, https://doi.org/10.1021/acscatal.3c03180. doi: 10.1021/acscatal.3c03180
33. [33]
  J. Liu, X. Ren, C. Li, M. Wang, H. Li, Q. Yang, Appl. Catal. B Environ. Energy. 310 (2022) 121314, https://doi.org/10.1016/j.apcatb.2022.121314. doi: 10.1016/j.apcatb.2022.121314
34. [34]
  L. Zhou, Z. Su, J. Wang, Y. Cai, N. Ding, L. Wang, J. Zhang, Y. Liu, J. Lei, Appl. Catal. B Environ. Energy. 341 (2024) 123290, https://doi.org/10.1016/j.apcatb.2023.123290. doi: 10.1016/j.apcatb.2023.123290
35. [35]
  H.B. Zhang, Z.L. Wang, J.F. Zhang, K. Dai, Chin. J. Catal. 49 (2023) 42, https://doi.org/10.1016/s1872-2067(23)64444-4. doi: 10.1016/s1872-2067(23)64444-4
36. [36]
  Y.M. Song, X.L. Zheng, Y.Q. Yang, Y.H. Liu, J. Li, D.X. Wu, W.F. Liu, Y.J. Shen, X.L. Tian, Adv. Mater. 36 (2024) 2305835, https://doi.org/10.1002/adma.202305835. doi: 10.1002/adma.202305835
37. [37]
  C. Chen, J. Zhang, H. Chu, L. Sun, G. Dawson, K. Dai, Chin. J. Catal. 63 (2024) 81, https://doi.org/10.1016/S1872-2067(24)60072-0. doi: 10.1016/S1872-2067(24)60072-0
38. [38]
  J. Yang, Z. Yang, K. Yang, Q. Yu, X. Zhu, H. Xu, H. Li, Chin. J. Catal. 44 (2023) 67, https://doi.org/10.1016/S1872-2067(22)64152-4. doi: 10.1016/S1872-2067(22)64152-4
39. [39]
  H.J. Zhang, Y.J. Gao, S.G. Meng, Z.R. Wang, P.X. Wang, Z.L. Wang, C.W. Qiu, S.F. Chen, B. Weng, Y.M. Zheng, Adv. Sci. 11 (2024) 2400099, https://doi.org/10.1002/advs.202400099. doi: 10.1002/advs.202400099
40. [40]
  Q.-L. Mo, J.-L. Li, S.-R. Xu, K. Wang, X.-Z. Ge, Y. Xiao, G. Wu, F.-X. Xiao, Adv. Funct. Mater. 33 (2023) 2210332, https://doi.org/10.1002/adfm.202210332. doi: 10.1002/adfm.202210332
41. [41]
  H. Chen, Y. Huang, C. Sha, J.M. Moradian, Y.-C. Yong, Z. Fang, Renew. Sustain. Energy Rev. 178 (2023) 113271, https://doi.org/10.1016/j.rser.2023.113271. doi: 10.1016/j.rser.2023.113271
42. [42]
  H. Zheng, Z. Huang, P. Wei, Y. Lin, Y. Cao, X. Zhang, B. Zhou, C. Peng, ACS Sustain. Chem. Eng. 13 (2025) 4078, https://doi.org/10.1021/acssuschemeng.4c10134. doi: 10.1021/acssuschemeng.4c10134
43. [43]
  Y. Zhou, Y. He, M. Gao, N. Ding, J. Lei, Y. Zhou, Chin. Chem. Lett. 35 (2024) 108690, https://doi.org/10.1016/j.cclet.2023.108690. doi: 10.1016/j.cclet.2023.108690
44. [44]
  F. Xing, J. Bai, M. Zhang, Y. Mao, J. Liu, Chemphotochem 9 (2025) e202400351, https://doi.org/10.1002/cptc.202400351. doi: 10.1002/cptc.202400351
45. [45]
  W. Li, L. Wan, Y. Dong, H. Luo, W. Li, T.P. Lai, J. Zhao, G. Liu, Y. Gao, Y. Deng, W. Hu, L. Zhang, Chem. Eng. J. 517 (2025) 164375, https://doi.org/10.1016/j.cej.2025.164375. doi: 10.1016/j.cej.2025.164375
46. [46]
  S. Zhang, Y. Zhang, Y. Chen, D. Yang, S. Li, Y. Wu, Y. Sun, Y. Cheng, J. Shi, Z. Jiang, ACS Catal. 11 (2021) 476, https://doi.org/10.1021/acscatal.0c04462. doi: 10.1021/acscatal.0c04462
47. [47]
  J. Shi, C. Tao, Z. Wang, Y. Dai, S. Zhang, J. Li, Y. Chen, X. Mao, Z. Jiang, Angew. Chem. Int. Ed. (2025) e202424995, https://doi.org/10.1002/anie.202424995. doi: 10.1002/anie.202424995
48. [48]
  Y. Liu, Y. Liu, Z. Yao, Z. Yu, H. Zhu, C. Xing, Y. Wang, X. Tan, Y. Huang, Y. Hou, S. Wang, Appl. Catal. B Environ. Energy. 371 (2025) 125275, https://doi.org/10.1016/j.apcatb.2025.125275. doi: 10.1016/j.apcatb.2025.125275
49. [49]
  A.-M. Manke, K. Geisel, A. Fetzer, P. Kurz, Phys. Chem. Chem. Phys. 16 (2014) 12029, https://doi.org/10.1039/C3CP55023K. doi: 10.1039/C3CP55023K
50. [50]
  S. Zhang, J. Shi, Y. Sun, Y. Wu, Y. Zhang, Z. Cai, Y. Chen, C. You, P. Han, Z. Jiang, ACS Catal. 9 (2019) 3913, https://doi.org/10.1021/acscatal.9b00255. doi: 10.1021/acscatal.9b00255
51. [51]
  V. Ganesan, D. Sivanesan, S. Yoon, Inorg. Chem. 56 (2017) 1366, https://doi.org/10.1021/acs.inorgchem.6b02474. doi: 10.1021/acs.inorgchem.6b02474
52. [52]
  S. Singh, R.K. Yadav, T.W. Kim, C. Singh, P. Singh, S. Chaubey, A.P. Singh, J.-O. Baeg, S.K. Gupta, D. Tiwary, Energy Fuels 36 (2022) 8402, https://doi.org/10.1021/acs.energyfuels.1c03697. doi: 10.1021/acs.energyfuels.1c03697
53. [53]
  H.C. Lo, C. Leiva, O. Buriez, J.B. Kerr, M.M. Olmstead, R.H. Fish, Inorg. Chem. 40 (2001) 6705, https://doi.org/10.1021/ic010562z. doi: 10.1021/ic010562z
54. [54]
  A. Marrone, R.H. Fish, J. Organomet. Chem. 943 (2021) 121810, https://doi.org/10.1016/j.jorganchem.2021.121810. doi: 10.1016/j.jorganchem.2021.121810
1. [1]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
2. [2]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . Highly Efficient InOOH/ZnIn₂S₄ Hollow Sphere S-Scheme Heterojunction with 0D/2D Interface for Enhancing Photocatalytic CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-0. doi: 10.3866/PKU.WHXB202407002
3. [3]
  Chengyan Ge , Jiawei Hu , Xingyu Liu , Yuxi Song , Chao Liu , Zhigang Zou . Self-integrated black NiO clusters with ZnIn₂S₄ microspheres for photothermal-assisted hydrogen evolution by S-scheme electron transfer mechanism. Acta Physico-Chimica Sinica, 2026, 42(1): 100154-0. doi: 10.1016/j.actphy.2025.100154
4. [4]
  Jiali Lei , Juan Wang , Wenhui Zhang , Guohong Wang , Zihui Liang , Jinmao Li . TiO₂/CdIn₂S₄ S-scheme heterojunction photocatalyst promotes photocatalytic hydrogen evolution coupled vanillyl alcohol oxidation. Acta Physico-Chimica Sinica, 2025, 41(12): 100174-0. doi: 10.1016/j.actphy.2025.100174
5. [5]
  Yanyan Zhao , Zhen Wu , Yong Zhang , Bicheng Zhu , Jianjun Zhang . Enhancing photocatalytic H₂O₂ production via dual optimization of charge separation and O₂ adsorption in Au-decorated S-vacancy-rich CdIn₂S₄. Acta Physico-Chimica Sinica, 2025, 41(11): 100142-0. doi: 10.1016/j.actphy.2025.100142
6. [6]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-0. doi: 10.3866/PKU.WHXB202309031
7. [7]
  Chengxin Chen , Hongfei Shi , Xiaoyan Cai , Liang Mao , Zhe Chen . Enhanced bifunctional photocatalytic performances for H₂ evolution and HCHO elimination with an S-scheme CoWO₄/CdIn₂S₄ heterojunction. Acta Physico-Chimica Sinica, 2025, 41(12): 100155-0. doi: 10.1016/j.actphy.2025.100155
8. [8]
  Honghong Zhang , Zhen Wei , Derek Hao , Lin Jing , Yuxi Liu , Hongxing Dai , Weiqin Wei , Jiguang Deng . 非均相催化CO₂与烃类协同催化转化的最新进展. Acta Physico-Chimica Sinica, 2025, 41(7): 100073-0. doi: 10.1016/j.actphy.2025.100073
9. [9]
  Yanzhe WANG , Xiaoming GUO , Qiangsheng GUO , Liang LI , Bin LU , Peihang YE . Effect of Ce introduction on the low-temperature performance of NiAl catalyst for CO₂ methanation. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2218-2228. doi: 10.11862/CJIC.20250202
10. [10]
  Wenlong Wang , Wentao Hao , Lang He , Jia Qiao , Ning Li , Chaoqiu Chen , Yong Qin . Bandgap and adsorption engineering of carbon dots/TiO₂ S-scheme heterojunctions for enhanced photocatalytic CO₂ methanation. Acta Physico-Chimica Sinica, 2025, 41(9): 100116-0. doi: 10.1016/j.actphy.2025.100116
11. [11]
  Yiting Huo , Xin Zhou , Feifan Zhao , Chenbin Ai , Zhen Wu , Zhidong Chang , Bicheng Zhu . Boosting photocatalytic CO₂ methanation through TiO₂/CdS S-scheme heterojunction and fs-TAS mechanism study. Acta Physico-Chimica Sinica, 2025, 41(11): 100148-0. doi: 10.1016/j.actphy.2025.100148
12. [12]
  Wenjuan SHI , Yuke LU , Xiuyuan LI , Lei HOU , Yaoyu WANG . Mg(Ⅱ) metal-organic frameworks based on biphenyltetracarboxylic acid: Synthesis and CO₂ adsorption and catalytic conversion performance. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2455-2463. doi: 10.11862/CJIC.20250220
13. [13]
  Xiaomin Kang , Chuanbao Jiao . Application of Metal-Organic Frameworks in CO₂ Catalytic Conversion: Promoting “Double Carbon” Actions for a Beautiful China. University Chemistry, 2026, 41(2): 208-217. doi: 10.12461/PKU.DXHX202503011
14. [14]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . Defective Ultrathin Two-Dimensional Materials for Photo-/Electrocatalytic CO₂ Reduction: Fundamentals and Perspectives. Acta Physico-Chimica Sinica, 2025, 41(3): 100019-0. doi: 10.3866/PKU.WHXB202308052
15. [15]
  Tieping CAO , Yuejun LI , Dawei SUN . Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 903-912. doi: 10.11862/CJIC.20240366
16. [16]
  Wenwen Ma , Lian Kong , Jinyang Chu , Li Ma , Ziqing Ma , Heyu Cheng , Xinyuan Li , Zhan Yu , Zhen Zhao . Digitalization-Driven Olefin Production: Digital Design of Catalysts for CO₂-Assisted Oxidation Dehydrogenation of Ethane to Ethylene. University Chemistry, 2026, 41(1): 363-372. doi: 10.12461/PKU.DXHX202506055
17. [17]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
18. [18]
  Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO₂ Reduction to C₂ Products and Superior Rechargeable Zn-CO₂ Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027
19. [19]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
20. [20]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(402)
HTML views(56)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Efficient photocatalytic NADH regeneration and enzymatic CO2 reduction over[Cp*Rh(bpy)H2O]2+ self-assembled CdIn2S4 flower-like microspheres

Metrics

通讯作者: 陈斌, bchen63@163.com

Efficient photocatalytic NADH regeneration and enzymatic CO₂ reduction over[Cp^*Rh(bpy)H₂O]²⁺ self-assembled CdIn₂S₄ flower-like microspheres