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Citation: Mi Tian, Haifeng Li, Lailai Wang. Highly efficient Rh(I)/tris-H₈-binaphthyl monophosphite catalysts for hydroformylation of dicyclopentadiene to dialdehydes[J]. Chinese Journal of Catalysis, ;2018, 39(10): 1646-1652. doi: 10.1016/S1872-2067(18)63098-0 shu

Highly efficient Rh(I)/tris-H₈-binaphthyl monophosphite catalysts for hydroformylation of dicyclopentadiene to dialdehydes

Mi Tian ^a,b, ,
Haifeng Li ^a ,
Lailai Wang ^a,c

a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c Guangzhou Lee & Man Technology Company Limited, Guangzhou 511458, Guangdong, China

Received Date: 30 March 2018
Revised Date: 7 May 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (21633013, 21073211, 21174155)and 2016 Nansha District Reasearch Project (2016GG007).

Novel catalytic systems for the Rh-catalyzed hydroformylation of dicyclopentadiene have been developed using tris-H₈-binaphthyl monophosphite as ligands containing different ester substituents at the 2'-binaphthyl position (OCOMe, OCOPh, OCOAdamantyl and OCOPhCl). The catalysts exhibited high activity (S/C=4000, TON=3286) with good to excellent selectivity towards dialdehydes. Remarkably, the Rh(I) complex bearing the ligands with chlorophenyl ester substituents led to 99.9% conversion and 98.7% selectivity for dialdehydes under relatively mild conditions (6 MPa, 120℃).
- Hydroformylation,
- Dicyclopentadiene,
- Monophosphite,
- Dialdehyde,
- Homogeneous catalysis
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通讯作者: 陈斌, bchen63@163.com

Highly efficient Rh(I)/tris-H₈-binaphthyl monophosphite catalysts for hydroformylation of dicyclopentadiene to dialdehydes