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Citation: Bai-Ling Chen, Zhen Wang, You-Can Zhang, Zhi-Gang Zhao, Zili Chen. Silver-catalyzed three-component reaction of phenyldiazoacetate with arylamine and imine[J]. Chinese Journal of Catalysis, ;2018, 39(10): 1594-1598. doi: 10.1016/S1872-2067(18)63088-8 shu

Silver-catalyzed three-component reaction of phenyldiazoacetate with arylamine and imine

a Department of Chemistry, Renmin University of China, Beijing 100872, China;
b College of Chemistry & Environment Protection Engineering, Southwest University for Nationalities, Chengdu 610041, Sichuan, China

Received Date: 26 March 2018
Revised Date: 23 April 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (21472237).

A new method was developed to diastereoselectively synthesize polysubstituted 1,2-diamine compounds from the reaction of diazoesters with arylamines and diaryl imines by using the dioxazoline ligand L₂-ligated silver catalyst. The Lewis acidity of the silver catalyst affected the different types of substrate diastereoselectivities; It also led to the formation of amine-exchange side products.
- Silver catalysis,
- Carbene transfer reaction,
- Three-component reaction,
- Ammonium ylide,
- Diamine compouds
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