Citation: Anhua Liu, Jinju Zhang, Xiaobing Lv. Novel hydrazine-bridged covalent triazine polymer for CO₂ capture and catalytic conversion[J]. Chinese Journal of Catalysis, ;2018, 39(8): 1320-1328. doi: 10.1016/S1872-2067(18)63040-2 shu

Novel hydrazine-bridged covalent triazine polymer for CO₂ capture and catalytic conversion

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, Liaoning, China

Received Date: 5 January 2018
Revised Date: 2 February 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (21406025), the China Postdoctoral Science Foundation (2014M551067), and the Start-Up Foundation of Dalian University of Technology (DUT13RC(3)58).

Carbon dioxide (CO₂) capture and catalytic conversion has become an attractive and challenging strategy for CO₂ utilization since it is an abundant, inexpensive, and renewable C1 resource and a main greenhouse gas. Herein, a novel hydrazine-bridged covalent triazine polymer (HB-CTP) was first designed and synthesized through simple polymerization of cyanuric chloride with 2,4,6-trihydrazinyl-1,3,5-triazine. The resultant HB-CTP exhibited good CO₂ capture capacity (8.2 wt%, 0℃, and 0.1 MPa) as well as satisfactory recyclability after five consecutive adsorption-desorption cycles. Such a polymer was subsequently employed as a metal-free heterogeneous catalyst for the cyclo-addition of CO₂ with various epoxides under mild and solvent-free conditions, affording cyclic carbonates with good to excellent yields (67%-99%) and high functional-group tolerance. The incorporation of hydrazine linkages into HB-CTP's architecture was suggested to play the key role in activating epoxides through hydrogen bonding. Moreover, HB-CTP can be reused at least five times without significant loss of its catalytic activity.
- Covalent triazine polymer,
- Capture,
- Catalysis,
- Carbon dioxide,
- Cyclic carbonate
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沈阳化工大学材料科学与工程学院沈阳 110142

Novel hydrazine-bridged covalent triazine polymer for CO2 capture and catalytic conversion

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通讯作者: 陈斌, bchen63@163.com

Novel hydrazine-bridged covalent triazine polymer for CO₂ capture and catalytic conversion