Citation: Liandi Wang, Tingting Liu. Ruthenium(Ⅱ) complex catalysts bearing a 2,6-bis(tetrazolyl)pyridine ligand for the transfer hydrogenation of ketones[J]. Chinese Journal of Catalysis, ;2018, 39(2): 327-333. doi: 10.1016/S1872-2067(17)62994-2 shu

Ruthenium(Ⅱ) complex catalysts bearing a 2,6-bis(tetrazolyl)pyridine ligand for the transfer hydrogenation of ketones

Liandi Wang ^a, ,
Tingting Liu ^a,b

a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 1 November 2017
Revised Date: 1 December 2017

Three ruthenium(Ⅱ) complex catalysts bearing 2,6-bis(tetrazolyl)pyridine were synthesized, structurally characterized, and applied in the transfer hydrogenation of ketones. Their different catalytic activities were attributed to the different phosphine ligands on the 4-chloro-2,6-bis(1-(p-tolyl)-1H-tetrazol-5-yl)pyridine ruthenium(Ⅱ) complexes, with that based on 1,4-bis(diphenylphosphino) butane exhibiting better catalytic activity. A variety of ketones were reduced to their corresponding alcohols with >95% conversion.
- 2,6-Bis(tetrazolyl)pyridine,
- Ruthenium,
- Transfer hydrogenation,
- Ketone,
- Homogeneous catalysis
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