Citation: Xiao-Na Li, Xiu-Ping Zou, Sheng-Gui He. Metal-mediated catalysis in the gas phase:A review[J]. Chinese Journal of Catalysis, ;2017, 38(9): 1515-1527. doi: 10.1016/S1872-2067(17)62782-7 shu

Metal-mediated catalysis in the gas phase:A review

a Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
b School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, Guangdong, China

Received Date: 30 November 2016
Revised Date: 5 January 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (21303215, 21325215, 21573246), the Major Research Plan of China (No. 2013CB834603) and the grant from the Youth Innovation Promotion Association, Chinese Academy of Sciences (2016030).

This review summarizes a variety of experimentally identified gas-phase catalytic cycles, all of which are mediated by atomic metal ions, bare metal clusters, metal oxide clusters or metal com-plexes. Emphasis is placed on the latest advances in the unique catalytic reactivity of clus-ter-confined single noble metal atoms. The cycles discussed in this paper cover a wide range of inorganic and organic molecules. The use of start-of-the-art mass spectrometric instrumentation in conjunction with quantum chemistry calculations is also reported, as these techniques have deter-mined the mechanistic details of the elementary steps of such catalytic cycles. The important role of gas-phase data in guiding the rational design of better-performing catalysts in related condensed phase reactions is also examined. In particular, this review focuses on the following three topics:(1) the catalytic oxidation of carbon monoxide, (2) the catalytic functionalization of methane, and (3) catalytic decarboxylation.
- Metal catalysis,
- Clusters,
- Single atom catalysts,
- Carbon monoxide,
- Methane
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