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Citation: Yongle Chen, Shiya Ding, Wentao Zheng, Yiyang Zhang, Youting Wu, Xingbang Hu. Proton-gradient-transfer acid complexes and their catalytic performance for the synthesis of geranyl acetate[J]. Chinese Journal of Catalysis, ;2016, 37(12): 2114-2121. doi: 10.1016/S1872-2067(16)62577-9 shu

Proton-gradient-transfer acid complexes and their catalytic performance for the synthesis of geranyl acetate

Separation Engineering Research Center, Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, Jiangsu, China

Received Date: 29 August 2016
Revised Date: 6 October 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (21376115, 21576129).

Special proton-gradient-transfer acid complexes (PGTACs) in which the bonded protons are not equivalent and have gradients in transfer ability, acidity, and reactivity were reported. The acidity gradient of the protons gave the PGTACs excellent catalytic activity and selectivity in the esterification of terpenols. These PGTACs are "reaction-induced self-separation catalysts" and can be easily reused. The kinetics with PGTACs as catalyst in the esterification of geraniol were also studied for use in engineering design.
- Geranyl acetate,
- Esterification,
- Kinetics,
- Proton gradient transfer,
- Reaction-induced self-separation catalyst
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