Citation: Tadahiro Fujitani, Isao Nakamura. Mechanism and active sites of CO oxidation over single-crystal Au surfaces and a Au/TiO₂(110) model surface[J]. Chinese Journal of Catalysis, ;2016, 37(10): 1676-1683. doi: 10.1016/S1872-2067(16)62516-0 shu

Mechanism and active sites of CO oxidation over single-crystal Au surfaces and a Au/TiO₂(110) model surface

National Institute of Advanced Industrial Science and Technology(AIST), 1-1-1 Higashi, Tsukuba 305-8565, Japan

Received Date: 8 April 2016
Revised Date: 27 July 2016

Fund Project: This work was financially supported by JST-CREST.

We describe the reaction mechanism and active sites for CO oxidation over a Au/TiO₂(110) model surface and Au single-crystal surfaces, along with the role of H₂O, on a molecular scale. At low temperature (<320 K), H₂O played an essential role in promoting CO oxidation, and the active site for CO oxidation was the perimeter of the interface between the gold nanoparticles and the TiO₂ support (Au^δ+-O^δ--Ti). We believe that the O-O bond was activated by the formation of OOH, which was produced directly from O₂ and H₂O at the perimeter of the interface between the gold nanoparticles and the TiO₂ support, and consequently OOH reacted with CO to form CO₂. This reaction mechanism explains the dependence of the CO₂ formation rate on O₂ pressure at 300 K. In contrast, at high temperature (>320 K), low-coordinated gold atoms built up on the surface as a result of surface reconstruction due to exposure to CO. The low-coordinated gold atoms adsorbed O₂, which then dissociated and oxidized CO on the metallic gold surface.
- Gold,
- Model catalyst,
- CO oxidation,
- Reaction mechanism,
- Active sites
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
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沈阳化工大学材料科学与工程学院沈阳 110142

Mechanism and active sites of CO oxidation over single-crystal Au surfaces and a Au/TiO2(110) model surface

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通讯作者: 陈斌, bchen63@163.com

Mechanism and active sites of CO oxidation over single-crystal Au surfaces and a Au/TiO₂(110) model surface