Citation: Longlong Geng, Jinling Song, Bin Zheng, Shujie Wu, Wenxiang Zhang, Mingjun Jia, Gang Liu. Aerobic oxidative coupling of alcohols and amines to imines over iron catalysts supported on mesoporous carbon[J]. Chinese Journal of Catalysis, ;2016, 37(9): 1451-1460. doi: 10.1016/S1872-2067(16)62506-8 shu

Aerobic oxidative coupling of alcohols and amines to imines over iron catalysts supported on mesoporous carbon

Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Changchun 130012, Jilin, China

Received Date: 30 May 2016
Revised Date: 12 July 2016

Fund Project: This work was supported by the National Natural Science Foundation of China(21473073, 21473074) and the "13th Five-Year" Science and Technology Research of the Education Department of Jilin Province(2016403).

Direct oxidative coupling of an alcohol and amine, with air or molecular oxygen as the oxygen source, is an environmentally friendly method for imine synthesis. We developed an Fe catalyst supported on mesoporous carbon(denoted by FeO_x/HCMK-3) for this reaction with excellent activity and recyclability. FeO_x/HCMK-3 was prepared by impregnating HNO₃-treated mesoporous carbon(CMK-3) with iron nitrate solution. The highly dispersed FeO_x species give FeO_x/HCMK-3 high reducibility and are responsible for the high catalytic performance. Imine synthesis over FeO_x/HCMK-3 follows a redox mechanism. The oxygen species in FeO_x/HCMK-3 participate in the reaction and are then regenerated by oxidation with molecular O₂. The reaction involves two consecutive steps: oxidative dehydrogenation of an alcohol to an aldehyde and coupling of the aldehyde with an amine to give an imine. Oxidative dehydrogenation of the alcohol is the rate-determining step in the reaction.
- Iron catalyst,
- Imine synthesis,
- Oxidative coupling,
- Mesoporous carbon,
- Molecular oxygen
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
1. [1]
  Zhang Xiaofei , Xu Shanhao , Wang Zhiyuan , He Long , Huang Tangcheng , Xu Yongming , Bian Yucui , Li Yike , Chen Haijun , Li Zhongjun . Surface doping of graphene into BiOCl for efficient photocatalytic amine coupling under visible light. Acta Physico-Chimica Sinica, 2026, 42(5): 100202-. doi: 10.1016/j.actphy.2025.100202
2. [2]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
3. [3]
  Chao WU , Qingxiu SHI , Tao XU , Zhengxi PENG , Zhongping XIONG , Yinglin ZHANG , Yujun SI , Chaozhong GUO . Enhancement of oxygen reduction reaction performance of iron-nitrogen doped carbon based catalysts by sodium carboxymethyl cellulose pre-deoxygenation. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 737-746. doi: 10.11862/CJIC.20250305
4. [4]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
5. [5]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
6. [6]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
7. [7]
  Ning CHEN , Jingle CHEN , Hongyuan ZHU , Huali CHEN , Liguang WU , Ting WANG . Mechanism and performance regulation of Co/Zr-doped mesoporous TiO₂ catalysts in activating sodium persulfate for tetracycline degradation. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 507-518. doi: 10.11862/CJIC.20250275
8. [8]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
9. [9]
  Meng Li , Haiyan Tan , Wenjun Zhu . Three-motif molecular junction photocatalysts with long-lived charge carriers for H₂O₂ production. Acta Physico-Chimica Sinica, 2026, 42(6): 100257-0. doi: 10.1016/j.actphy.2026.100257
10. [10]
  Yan LI , Gongxuan LÜ . Au and Pt-loaded nickel-iron layered hydroxide dual-site catalyst for efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1463-1474. doi: 10.11862/CJIC.20260032
11. [11]
  Haiqiang Lin , Weizheng Weng , Jingdong Lin , Mingshu Chen , Xueming Fang , Lefu Yang . Diverse Variables-Driven Catalytic Optimization: Experimental Enhancement and Instructional Design for Selective Methane Oxidation on Supported Nickel-based Catalysts. University Chemistry, 2025, 40(11): 327-336. doi: 10.12461/PKU.DXHX202505106
12. [12]
  Kangjuan Cheng , Chunxiao Liu , Youpeng Wang , Qiu Jiang , Tingting Zheng , Xu Li , Chuan Xia . Design of noble metal catalysts and reactors for the electrosynthesis of hydrogen peroxide. Acta Physico-Chimica Sinica, 2025, 41(10): 100112-0. doi: 10.1016/j.actphy.2025.100112
13. [13]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
14. [14]
  Ruifeng CHEN , Chao XU , Jianting JIANG , Tianshe YANG . Gold nanorod/zinc oxide/mesoporous silica nanoplatform: A triple-modal platform for synergistic anticancer therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2272-2282. doi: 10.11862/CJIC.20250117
15. [15]
  Yinjie Xu , Suiqin Li , Lihao Liu , Jiahui He , Kai Li , Mengxin Wang , Shuying Zhao , Chun Li , Zhengbin Zhang , Xing Zhong , Jianguo Wang . Enhanced Electrocatalytic Oxidation of Sterols using the Synergistic Effect of NiFe-MOF and Aminoxyl Radicals. Acta Physico-Chimica Sinica, 2024, 40(3): 2305012-0. doi: 10.3866/PKU.WHXB202305012
16. [16]
  Bin Liu . Teaching case design of chemistry “101 Plan” syntheticchemistry experiment course: taking the experiment of preparation of platinum nanocatalyst supported on carbon and determination of its electrochemical catalytic performance of methanol oxidation as an example. University Chemistry, 2026, 41(6): 125-135. doi: 10.12461/PKU.DXHX202506043
17. [17]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
18. [18]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
19. [19]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
20. [20]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1090)
HTML views(89)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142