Citation: Pongsaton Amornpitoksuk, Sumetha Suwanboon. Photocatalytic degradation of dyes by AgBr/Ag₃PO₄ and the ecotoxicities of their degraded products[J]. Chinese Journal of Catalysis, ;2016, 37(5): 711-719. doi: 10.1016/S1872-2067(15)61078-6 shu

Photocatalytic degradation of dyes by AgBr/Ag₃PO₄ and the ecotoxicities of their degraded products

Pongsaton Amornpitoksuk ^a,c,, ,
Sumetha Suwanboon ^b,c

1.
a Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla, 90112 Thailand;
2.
b Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla, 90112 Thailand;
3.
c Center of Excellence in Nanotechnology for Energy (CENE), Prince of Songkla University, Hat-Yai, Songkhla, 90112 Thailand

Corresponding author: Pongsaton Amornpitoksuk,
Received Date: 14 January 2016
Available Online: 3 March 2016

Ag₃PO₄ powders were prepared through a precipitation reaction between AgNO₃ and precipitating agent solutions that were prepared by adjusting the amount of H₃PO₄ in the Na₃PO₄solutions. The Ag₃PO₄ powders prepared from the precipitation solution with a pH of 6 showed the highest photocatalytic activity for decolorizing the methylene blue and rhodamine B dyes. These Ag₃PO₄ powders were further modified by the addition of KBr solutions to obtain AgBr/Ag₃PO₄ powders and these photocatalysts can decolorize the anionic dyes as reactive orange and methyl orange. The reactive species involved in the photocatalytic degradation process were evaluated for their inhibitory activity using the appropriate scavengers. After photocatalysis, mass spectrometry confirmed that the dyes were degraded to smaller molecules. The ecotoxicities of the dye solutions before and after treatment were evaluated by studying their ability to inhibit the growth of the bioindicator Chlorella vulgaris.
- Silver phosphate,
- Silver bromide,
- Photocatalytic degradation,
- One-pot synthesis,
- Ecotoxicity
1. [1]
  [1] M.A. Lazar, S. Varghese, S.S. Nair, Catalysts, 2012, 2, 572-601.
2. [2]
  [2] Z. G, Yi, J. H. Ye, N. Kikugawa, T. Kako, S. X. Ouyang, H. Stuart-Williams, H. Yang, J. Y. Cao, W. J. Luo, Z. S. Li, Y. Liu, R. L. Withers, Nat. Mater., 2010, 9, 559-564.
3. [3]
  [3] Y. S. Xu, W. D. Zhang, CrystEngComm, 2013, 15, 5407-5411.
4. [4]
  [4] P. Amornpitoksuk, K. Intarasuwan, S. Suwanboon, J. Baltrusaitis, Ind. Eng. Chem. Res., 2013, 52, 17369-17375.
5. [5]
  [5] J. Wang, S. Q. Lou, P. Sun, L. L. Wang, Y. R. Teng, M. D. Chen, F. Teng, ChemCatChem, 2014, 6, 2021-2027.
6. [6]
  [6] H. Wang, Y. S. Bai, J. T. Yang, X. F. Lang, J. H. Li, L. Guo, Chem. Eur. J., 2012, 18, 5524-5529.
7. [7]
  [7] A. Khan, M. Qamar, M. Muneer, Chem. Phys. Lett., 2012, 519-520, 54-58.
8. [8]
  [8] Z. B. Jiao, Y. Zhang, H. C. Yu, G. X. Lu, J. H. Ye, Y. P. Bi, Chem. Commun., 2013, 49, 636-638.
9. [9]
  [9] >Y. P. Bi, S. X. Ouyang, J. Y. Cao, J. H. Ye, Phys. Chem. Chem. Phys., 2011, 13, 10071-10075.
10. [10]
  [10] J. Cao, B. D. Luo, H. L. Lin, B. Y. Xu, S. F. Chen, J. Hazard. Mater., 2012, 217-218, 107-113.
11. [11]
  [11] P. Amornpitoksuk, S. Suwanboon, Adv. Powder Mater., 2014, 25, 1026-1030.
12. [12]
  [12] B. Thongrom, P. Amornpitoksuk, S. Suwanboon, J. Baltrusaitis, Korean J. Chem. Eng., 2014, 31, 587-592.
13. [13]
  [13] A. Indra, P.W. Menezes, M. Schwarze, M. Driess, New J. Chem., 2014, 38, 1942-1945.
14. [14]
  [14] P. Y. Dong, Y. H. Wang, H. H. Li, H. Li, X. L. Ma, L. L. Han, J. Mater. Chem. A, 2013, 1, 4651-4656.
15. [15]
  [15] M. Ge, N. Zhu, Y. P. Zhao, J. Li, L. Liu, Ind. Eng. Chem. Res., 2012, 51, 5167-5173.
16. [16]
  [16] H. Katsumata, T. Hayashi, M. Taniguchi, T. Suzuki, S. Kaneco, Mater. Sci. Semicond. Process., 2014, 25, 68-75.
17. [17]
  [17] Y. F. Wang, X. L. Li, Y. W. Wang, C. M. Fan, J. Solid State Chem., 2013, 202, 51-56.
1. [1]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
2. [2]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
3. [3]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
4. [4]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
5. [5]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
6. [6]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
7. [7]
  Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
8. [8]
  Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu₂O/Bi₂CrO₆ Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403
9. [9]
  Qingwang LIU . MoS₂/Ag/g-C₃N₄ Z-scheme heterojunction: Preparation and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 821-832. doi: 10.11862/CJIC.20240148
10. [10]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
11. [11]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
12. [12]
  Xiaojun Wu , Kai Hu , Faqiong Zhao . Laying the Groundwork for General Chemistry Experiment Teaching: Exploration and Summary of Assisting Experiment Preparatory Work through Online and Offline Integration. University Chemistry, 2024, 39(8): 23-27. doi: 10.3866/PKU.DXHX202312052
13. [13]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
14. [14]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
15. [15]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
16. [16]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
17. [17]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . 自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-. doi: 10.1016/j.actphy.2025.100050
18. [18]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . 调节O,S共掺杂C₃N₄中的活性氧生成以促进光催化降解微塑料. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-. doi: 10.1016/j.actphy.2025.100052
19. [19]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
20. [20]
  Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(535)
HTML views(60)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Photocatalytic degradation of dyes by AgBr/Ag3PO4 and the ecotoxicities of their degraded products

Metrics

通讯作者: 陈斌, bchen63@163.com

Photocatalytic degradation of dyes by AgBr/Ag₃PO₄ and the ecotoxicities of their degraded products