Citation: Ying Zhou, Jilan Long, Yingwei Li. Ni-based catalysts derived from a metal-organic framework for selective oxidation of alkanes[J]. Chinese Journal of Catalysis, ;2016, 37(6): 955-962. doi: 10.1016/S1872-2067(15)61067-1 shu

Ni-based catalysts derived from a metal-organic framework for selective oxidation of alkanes

State Key Laboratory of Pulp and Paper Engineering, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China

Received Date: 27 January 2016
Revised Date: 25 February 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (21322606, 21436005, 21576095), the State Key Laboratory of Pulp and Paper Engineering (2015TS03), the Doctoral Fund of Ministry of Education of China (20120172110012), Fundamental Research Funds for the Central Universities (2015ZP002, 2015PT004), and Guangdong Natural Science Foundation (2013B090500027).

Ni nanoparticles embedded in nitrogen-doped carbon (Ni@C-N) materials were prepared by thermolysis of a Ni-containing metal-organic framework (Ni-MOF) under inert atmosphere. The as-synthesized Ni@C-N materials were characterized by powder X-ray diffraction, N₂ adsorption-desorption analysis, scanning electron microscopy, transmission electron microscopy, atomic absorption spectroscopy, and X-ray photoelectron spectroscopy. The MOF-derived Ni-based materials were then examined as heterogeneous catalysts for the oxidation of alkanes under mild reaction conditions. The Ni@C-N composites displayed high activity and selectivity toward the oxidation of a variety of saturated C-H bonds, affording the corresponding oxidation products in good-to-excellent yields. Furthermore, the catalysts could be recycled and reused for at least four times without any significant loss in activity and selectivity under the investigated conditions.
- Nickel,
- Nanoparticle,
- Metal-organic framework,
- Alkane,
- Oxidation,
- Heterogeneous catalysis
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