Citation: Mohammad Ali Dadvar, Razieh Fazaeli. Application of sodium titanate nanotubes doped with vanadium (VNaTNT) as a heterogeneous catalyst for oxidation of sulfides at room temperature[J]. Chinese Journal of Catalysis, ;2016, 37(4): 494-501. doi: 10.1016/S1872-2067(15)61056-7 shu

Application of sodium titanate nanotubes doped with vanadium (VNaTNT) as a heterogeneous catalyst for oxidation of sulfides at room temperature

Mohammad Ali Dadvar ,
Razieh Fazaeli ^,

1.
Department of Chemistry, Shahreza Branch, Islamic Azad University, 86145-311, Iran

Corresponding author: Razieh Fazaeli,
Received Date: 31 December 2015
Available Online: 4 February 2016

A heterogeneous titanate nanotube (TNT) catalyst containing TiO₂, Na, and V has been synthesized and used in the chemoselective oxidation of sulfides to the corresponding sulfoxides in the presence of 30% H₂O₂ in water. Some of the advantages of our method include excellent yields, heterogeneous conditions, simplicity, compatibility with a variety of functionalities, and ease of isolation of the products. Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and N₂ adsorption were used for structural and textural characterization of the catalyst (VNaTNT).
- Sulfide,
- Sulfoxide,
- Sulfone,
- Supported vanadia catalyst,
- Nanotube
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