Citation: Masoumeh Taei, Fardin Abedi. New modified multiwalled carbon nanotubes paste electrode for electrocatalytic oxidation and determination of warfarin in biological and pharmaceutical samples[J]. Chinese Journal of Catalysis, ;2016, 37(3): 436-445. doi: 10.1016/S1872-2067(15)61039-7 shu

New modified multiwalled carbon nanotubes paste electrode for electrocatalytic oxidation and determination of warfarin in biological and pharmaceutical samples

Masoumeh Taei ^, ,
Fardin Abedi

1.
Chemistry Department, Payame Noor University, Tehran 19395-4697, Iran

Corresponding author: Masoumeh Taei,
Received Date: 12 September 2015
Available Online: 8 January 2016

A novel sensor for the determination of warfarin based on a simple and sensitive method was developed on multiwalled-carbon-nanotube modified ZnCrFeO₄ carbon paste electrodes (MWCNT/ZnCrFeO₄/CPEs). Cyclic voltammetry, differential pulse voltammetry, chronoamperometry, and electrochemical impedance spectroscopy were used to investigate the electrochemical behavior of warfarin at the chemically modified electrode. According to the results, MWCNT/ZnCrFeO₄/CPEs showed high electrocatalytic activity for warfarin oxidation, producing a sharp oxidation peak current at about +0.97 vs Ag/AgCl reference electrode at pH = 4.0. The peak current was linearly dependent on warfarin concentration over the range of 0.02-920.0 µmol/L with a detection limit of 0.003 µmol/L. In addition, chronoamperometry was also used to determine warfarin's catalytic rate constant and diffusion coefficient at MWCNT/ZnCrFeO₄/CPEs.
- ZnCrFeO₄Multiwalled carbon nanotubes,
- Warfarin,
- Electrochemical impedance spectroscopy,
- Paste electrode,
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