Citation: Sunfeng Li, Xing Wang, Qinqin He, Qi Chen, Yanli Xu, Hanbiao Yang, Mengmeng Lü, Fengyu Wei, Xueting Liu. Synergistic effects in N-K₂Ti₄O₉/UiO-66-NH₂ composites and their photocatalysis degradation of cationic dyes[J]. Chinese Journal of Catalysis, ;2016, 37(3): 367-377. doi: 10.1016/S1872-2067(15)61033-6 shu

Synergistic effects in N-K₂Ti₄O₉/UiO-66-NH₂ composites and their photocatalysis degradation of cationic dyes

1.
Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, Anhui, China

Corresponding author: Fengyu Wei, Xueting Liu,
Received Date: 28 October 2015
Available Online: 12 December 2015
Fund Project: 国家自然科学基金(51372062) (51372062)安徽省自然科学基金(1508085MB28,1308085MB21). (1508085MB28,1308085MB21)

N-K₂Ti₄O₉/UiO-66-NH₂ composites synthesized by a facile solvothermal method have a core-shell structure with UiO-66-NH₂ forming the shell around a N-K₂Ti₄O₉ core. Their photocatalytic activities in the degradation of dyes under visible light irradiation were investigated. The N-K₂Ti₄O₉/UiO-66-NH₂ composites exhibited higher photocatalytic activity than the pure components. This synergistic effect was due to the high adsorption capacity of UiO-66-NH₂ and that the two components together induced an enhanced separation efficiency of photogenerated electron-hole pairs. The mass ratio of N-K₂Ti₄O₉ to ZrCl₄ of 3:7 in the composite exhibited the highest photocatalytic activity. Due to the electrostatic attraction between the negatively charged backbone of UiO-66-NH₂ with the positively charged groups of cationic dyes, the composites were more photocatalytically active for cationic dyes than for anionic dyes.
- Nitrogen-doped potassium titamate,
- UiO-66-NH₂,
- Selective photocatalysis,
- Synergistic effect,
- Composite
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Synergistic effects in N-K2Ti4O9/UiO-66-NH2 composites and their photocatalysis degradation of cationic dyes

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Synergistic effects in N-K₂Ti₄O₉/UiO-66-NH₂ composites and their photocatalysis degradation of cationic dyes