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Citation: Bingyang Bai, Qi Qiao, Junhua Li, Jiming Hao. Synthesis of three-dimensional ordered mesoporous MnO2 and its catalytic performance in formaldehyde oxidation[J]. Chinese Journal of Catalysis, ;2016, 37(1): 27-31. doi: 10.1016/S1872-2067(15)61026-9 shu

Synthesis of three-dimensional ordered mesoporous MnO2 and its catalytic performance in formaldehyde oxidation

  • 1.

    a State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China;

  • 2.

    b Key Laboratory of Eco-Industry of the Ministry of Environmental Protection, Chinese Research Academy of Environmental Sciences, Beijing 100012, China;

  • 3.

    c State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China

  • Corresponding author: Qi Qiao,  Junhua Li, 
  • Received Date: 28 May 2015
    Available Online: 7 July 2015

    Fund Project: 国家自然科学基金(21325731, 21221004, 51478241). (21325731, 21221004, 51478241)

  • Three-dimensional (3D) ordered mesoporous MnO2 was prepared using KIT-6 mesoporous molecular sieves as a hard template. The material was used for catalytic oxidation of HCHO. The material has high surface areas and the mesoporous characteristics of the template, with cubic symmetry (ia3d). It consists of a β-MnO2 crystalline phase corresponding to pyrolusite, with a rutile structure. Transmission electron microscopy and X-ray photoelectron spectroscopy showed that the 3D-MnO2 catalyst has a large number of exposed Mn4+ ions on the (110) crystal plane surfaces, with a lattice spacing of 0.311 nm; this enhances oxidation of HCHO. Complete conversion of HCHO to CO2 and H2O was achieved at 130 ℃ on 3D-MnO2; the same conversions on α-MnO2 and β-MnO2 nanorods were obtained at 140 and 180 ℃, respectively, under the same conditions. The specific mesoporous structure, high specific surface area, and large number of surface Mn4+ ions are responsible for the catalytic activity of 3D-MnO2 in HCHO oxidation.
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