Citation: Alireza Khorshidi. Ruthenium nanoparticles supported on mesoporous MCM-41 as an efficient and reusable catalyst for selective oxidation of arenes under ultrasound irradiation[J]. Chinese Journal of Catalysis, ;2016, 37(1): 153-158. doi: 10.1016/S1872-2067(15)61001-4 shu

Ruthenium nanoparticles supported on mesoporous MCM-41 as an efficient and reusable catalyst for selective oxidation of arenes under ultrasound irradiation

Alireza Khorshidi ^,

1.
Department of Chemisty, Faculty of Sciences, University of Guilan, P. O. Box 41335-1914, Guilan, Rasht, Iran

Corresponding author: Alireza Khorshidi,
Received Date: 9 October 2015
Available Online: 24 October 2015
Fund Project:

Mesoporous MCM-41 was used as a support for the uniform dispersion of ruthenium nanoparticles having an average particle size of ~5 nm. The obtained nanocomposite, MCM-41-Ru, was characterized using inductively coupled plasma, transmission electron microscopy, energy dispersive X-ray analysis, X-ray diffraction, and BET surface area measurements. The material was employed as an efficient and recyclable catalyst in the ultrasound-assisted oxidation of arenes. It was observed that ultrasound irradiation in combination with KBrO₃ as the oxidant, in the presence of MCM-41-Ru nanoparticles, accelerates the oxidation reaction to afford the desired products in good yields. The recovered catalyst retained activity for successive runs, with a continuous change in the nature of its active sites.
- Nanoparticle,
- Ultrasound,
- Ruthenium,
- Arene oxidation,
- MCM-41
1. [1]
  [1] R. Parella, S. A. Babu Naveen, Catal. Commun., 2012, 29, 118.
2. [2]
  [2] A. Khalil, A. Fihri, M. Jouiad, R. Hashaikeh, Tetrahedron Lett., 2014, 55, 5973.
3. [3]
  [3] E. A. Karakhanov, A. L. Maksimov, E. M. Zakharian, Y. S. Kardasheva, S. V. Savilov, N. I. Truhmanova, A. O. Ivanov, V. A. Vinokurov, J. Mol. Catal. A, 2015, 397, 1.
4. [4]
  [4] P. Puthiaraj, W. S. Ahn, Catal. Commun., 2015, 65, 91.
5. [5]
  [5] M. Hałupka-Bryl, M. Bednarowicz, B. Dobosz, R. Krzyminiewski, T. Zalewski, B. Wereszczyńska, G. Nowaczyk, M. Jarek, Y. Nagasaki, J. Magn. Magn. Mater., 2015, 384, 320.
6. [6]
  [6] J. Kreuter, Adv. Drug Deliver. Rev., 2014, 71, 2.
7. [7]
  [7] J. Li, Y. J. Wang, X. J. An, Y. T. Tu, R. J. Liang, K. Wang, G. X. Shen, J. T. Zhu, J. Tao, Nanomed. Nanotechnol. Biol. Med., 2015, 11, 769.
8. [8]
  [8] J. Suárez-Cerda, G. A. Nuñez, H. Espinoza-Gómez, L. Z. Flores-López Mater. Sci. Eng. C, 2014, 43, 21.
9. [9]
  [9] R. A. Pascal Jr, W. D. McMillan, D. Van Engen., R. G. Eason, J. Am. Chem. Soc., 1987, 109, 4660.
10. [10]
  [10] C. Kazunga, M. D. Aitken, Appl. Environ. Microbiol., 2000, 66, 1917.
11. [11]
  [11] E. Guthrie-Nichols, A. Grasham, C. Kazunga, R. Sangaiah, A. Gold, J. Bortiatynski, M. Salloum, P. Hatcher, Environ. Toxicol. Chem., 2003, 22, 40.
12. [12]
  [12] R. L. Funk, E. R. R. Young, R. M. Williams, M. F. Flanagan, T. L. Cecil, J. Am. Chem. Soc., 1996, 118, 3291.
13. [13]
  [13] C. Tintel, J. Terheijden, J. Lugtenburg, J. Cornelisse, Tetrahedron Lett., 1987, 28, 2057.
14. [14]
  [14] Y. Li, B. Li, T. Chen, Z. C. Zhou, J. Wang, J. Huang, Chin. J. Catal., 2015, 36, 1086.
15. [15]
  [15] W. J. Mijs, C. R. H. I. De Jonge, Organic Syntheses by Oxidation with Metal Compounds, Springer, New York, 1986.
16. [16]
  [16] M. Hudlicky, Oxidations in Organic Chemistry, American Chemical Society, Washington DC, 1990.
17. [17]
  [17] Z. M. Zheng, J. P. Obbard, Enzyme Microb. Technol., 2002, 31, 3.
18. [18]
  [18] F. G. Oberender, J. A. Dixon, J. Org. Chem., 1959, 24, 1226.
19. [19]
  [19] F. X. Webster, J. Rivas-Enterrios, R. M. Silverstein, J. Org. Chem., 1987, 52, 689.
20. [20]
  [20] S. Torii, T. Inokuchi, K. Kondo, J. Org. Chem., 1985, 50, 4980.
21. [21]
  [21] T. K. M. Shing, V. W. F. Tai, E. K. W. Tam, Angew. Chem. Int. Ed., 1994, 33, 2312.
22. [22]
  [22] G. Balavoine, C. Eskenazi, F. Meunier, H. Riviere, Tetrahedron Lett., 1984, 25, 3187.
23. [23]
  [23] A. J. Bailey, W. P. Griffith, A. J. P. White, D. J. Williams, J. Chem. Soc., Chem. Commun., 1994, 1833.
24. [24]
  [24] J. Hu, D. Zhang, F. W. Harris, J. Org. Chem., 2005, 70, 707.
25. [25]
  [25] K. Tabatabaeian, M. Mamaghani, N. O. Mahmoodi, A. Khorshidi, Catal. Commun., 2008, 9, 416.
26. [26]
  [26] K. E. Pryor, G. W. Shipps Jr, D. A. Skyler, J. Rebek Jr, Tetrahedron, 1998, 54, 4107.
27. [27]
  [27] L. M. Stock, S. H. Wang, Energy Fuels, 1989, 3, 533.
28. [28]
  [28] R. Jeyaraman, R. W. Murray, J. Am. Chem. Soc., 1984, 106, 2462.
29. [29]
  [29] J. M. Kim, J. H. Kwak, S. Jun, R. Ryoo, J. Phys. Chem., 1995, 99, 16742.
30. [30]
  [30] S. Yamazaki, Tetrahedron Lett., 2001, 42, 3355.
31. [31]
  [31] H. R. Khavasi, S. S. H. Davarani, N. Safari, J. Mol. Catal. A, 2002, 188, 115.
32. [32]
  [32] Y. D. Kim, A. P. Seitsonen, S. Wendt, J. Wang, C. Fan, K. Jacobi, H. Over, G. Ertl, J. Phys. Chem. B, 2001, 105, 3752.
33. [33]
  [33] H. C. Liu, E. Iglesia, J. Phys. Chem. B, 2005, 109, 2155.
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