Citation: Alireza Khorshidi. Ruthenium nanoparticles supported on mesoporous MCM-41 as an efficient and reusable catalyst for selective oxidation of arenes under ultrasound irradiation[J]. Chinese Journal of Catalysis, ;2016, 37(1): 153-158. doi: 10.1016/S1872-2067(15)61001-4 shu

Ruthenium nanoparticles supported on mesoporous MCM-41 as an efficient and reusable catalyst for selective oxidation of arenes under ultrasound irradiation

Alireza Khorshidi ^,

1.
Department of Chemisty, Faculty of Sciences, University of Guilan, P. O. Box 41335-1914, Guilan, Rasht, Iran

Corresponding author: Alireza Khorshidi,
Received Date: 9 October 2015
Available Online: 24 October 2015
Fund Project:

Mesoporous MCM-41 was used as a support for the uniform dispersion of ruthenium nanoparticles having an average particle size of ~5 nm. The obtained nanocomposite, MCM-41-Ru, was characterized using inductively coupled plasma, transmission electron microscopy, energy dispersive X-ray analysis, X-ray diffraction, and BET surface area measurements. The material was employed as an efficient and recyclable catalyst in the ultrasound-assisted oxidation of arenes. It was observed that ultrasound irradiation in combination with KBrO₃ as the oxidant, in the presence of MCM-41-Ru nanoparticles, accelerates the oxidation reaction to afford the desired products in good yields. The recovered catalyst retained activity for successive runs, with a continuous change in the nature of its active sites.
- Nanoparticle,
- Ultrasound,
- Ruthenium,
- Arene oxidation,
- MCM-41
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