Citation: Vladimir V. Chesnokov, Olga Yu. Podyacheva, Alexander N. Shmakov, Lidiya S. Kibis, Andrei I. Boronin, Zinfer R. Ismagilov. Comparison of growth mechanisms of undoped and nitrogen-doped carbon nanofibers on nickel-containing catalysts[J]. Chinese Journal of Catalysis, ;2016, 37(1): 169-176. doi: 10.1016/S1872-2067(15)60982-2 shu

Comparison of growth mechanisms of undoped and nitrogen-doped carbon nanofibers on nickel-containing catalysts

1.
a Boreskov Institute of Catalysis, Novosibirsk 630090, Russia;
2.
b Novosibirsk State University, Novosibirsk 630090, Russia;
3.
c Institute of Coal Chemistry and Materials Science, Kemerovo 650000, Russia

Corresponding author: Olga Yu. Podyacheva,
Received Date: 28 August 2015
Available Online: 30 September 2015

The growth mechanisms of carbon nanofibers on Ni catalysts and nitrogen-doped carbon nanofibers on Ni and Ni-Cu catalysts were studied. The growth of both types of nanofibers was found to occur by a mechanism that included the formation of surface non-stoichiometric nickel carbide followed by the dissolution and diffusion of carbon, or carbon and nitrogen into the bulk of the catalyst particles.
- Carbon nanofibers,
- Nitrogen doping,
- Growth mechanism,
- Nickel-based catalyst
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