Citation: Bahaa M. Abu-Zied, Abdullah M. Asiri. The role of alkali promoters in enhancing the direct N₂O decomposition reactivity over NiO catalysts[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1837-1845. doi: 10.1016/S1872-2067(15)60963-9 shu

The role of alkali promoters in enhancing the direct N₂O decomposition reactivity over NiO catalysts

Bahaa M. Abu-Zied ^a,b,c,, ,
Abdullah M. Asiri ^a,c

1.
a Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah 21589, Saudi Arabia;

Corresponding author: Bahaa M. Abu-Zied,
Received Date: 5 May 2015
Available Online: 21 August 2015

Direct N₂O decomposition has been investigated over bare NiO and a series of its alkali-promoted catalysts. These catalysts were characterized by X-ray diffractometry, X-ray photoelectron spectroscopy (XPS) and field emission scanning electron microscopy. XPS analysis revealed that surface nickel is present in three forms: metal particles, NiO and Ni(OH)₂. It is suggested that nickel(0) valent atoms are essential for the interaction with N₂O molecules at the catalyst surfaces. Bare NiO exhibited a very low N₂O decomposition reactivity. However, the alkali-containing catalysts exhibited a marked activity enhancement.
- N₂O decomposition,
- Greenhouse gas,
- NiO,
- Alkali-promotion,
- Activity enhancement
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The role of alkali promoters in enhancing the direct N₂O decomposition reactivity over NiO catalysts