Citation: Xin Zhao, Lei Huang, Hongrui Li, Hang Hu, Jin Han, Liyi Shi, Dengsong Zhang. Highly dispersed V₂O₅/TiO₂ modified with transition metals (Cu, Fe, Mn, Co) as efficient catalysts for the selective reduction of NO with NH₃[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1886-1899. doi: 10.1016/S1872-2067(15)60958-5 shu

Highly dispersed V₂O₅/TiO₂ modified with transition metals (Cu, Fe, Mn, Co) as efficient catalysts for the selective reduction of NO with NH₃

Xin Zhao ^a ,
Lei Huang ^a,, ,
Hongrui Li ^a ,
Hang Hu ^a ,
Jin Han ^a ,
Liyi Shi ^b,, ,
Dengsong Zhang ^a,,

1.
a Research Center of Nano Science and Technology, Shanghai University, Shanghai 200444, China;

Corresponding author: Lei Huang, Liyi Shi, Dengsong Zhang,
Received Date: 18 June 2015
Available Online: 25 July 2015
Fund Project: 国家自然科学基金(21303099) (21303099) 国家重点基础研究发展计划(973计划, 2014CB660803) (973计划, 2014CB660803) 上海市教委项目(14ZZ097, B.3704713001) (14ZZ097, B.3704713001) 上海大学创新基金(K.10040713003). (K.10040713003)

Different transition metals were used to modify V₂O₅-based catalysts (M-V, M = Cu, Fe, Mn, Co) on TiO₂ via impregnation, for the selective reduction of NO with NH₃. The introduced metals induced high dispersion in the vanadium species and the formation of vanadates on the TiO₂ support, and increased the amount of surface acid sites and the strength of these acids. The strong acid sites might be responsible for the high N₂ selectivity at higher temperatures. Among these catalysts, Cu-V/TiO₂ showed the highest activity and N₂ selectivity at 225-375 ℃. The results of X-ray photoelectron spectroscopy, NH₃-temperature-programmed desorption, and in-situ diffuse reflectance infrared Fourier transform spectroscopy suggested that the improved performance was probably due to more active surface oxygen species and increased strong surface acid sites. The outstanding activity, stability, and SO₂/H₂O durability of Cu-V/TiO₂ make it a candidate to be a NO_x removal catalyst for stationary flue gas.
- deNO_x,
- Selective catalytic reduction,
- Vanadate,
- Transition metal
1. [1]
  [1] Zhang L, Shi L Y, Huang L, Zhang J P, Gao R H, Zhang D S. ACS Catal, 2014, 4: 1753
2. [2]
  [2] Kamolphop U, Taylor S F R, Breen J P, Burch R, Delgado J J, Chansai S, Hardacre C, Hengrasmee S, James S L. ACS Catal, 2011, 1: 1257
3. [3]
  [3] Deka U, Lezcano-Gonzalez I, Weckhuysen B M, Beale A M. ACS Catal, 2013, 3: 413
4. [4]
  [4] Maitarad P, Zhang D S, Gao R H, Shi L Y, Li H R, Huang L, Rungrotmongkol T, Zhang J P. J Phys Chem C, 2013, 117: 9999
5. [5]
  [5] Chen L, Li J H, Ge M F. J Phys Chem C, 2009, 113: 21177
6. [6]
  [6] Ettireddy P R, Ettireddy N, Boningari T, Pardemann R, Smirniotis P G. J Catal, 2012, 292: 53
7. [7]
  [7] Phil H H, Reddy M P, Kumar P A, Ju L K, Hyo J S. Appl Catal B, 2008, 78: 301
8. [8]
  [8] Bai S L, Zhao J H, Wang L, Zhu Z P. Catal Today, 2010, 158: 393
9. [9]
  [9] Kompio P G W A, Brückner A, Hipler F, Auer G, Löffler E, Grünert W. J Catal, 2012, 286: 237
10. [10]
  [10] Putluru S S R, Schill L, Gardini D, Mossin S, Wagner J B, Jensen A D, Fehrmann R. J Mater Sci, 2014, 49: 2705
11. [11]
  [11] Camposeco R, Castillo S, Mugica V, Mejía-Centeno I, Marín J. Chem Eng J, 2014, 242: 313
12. [12]
  [12] Koh H L, Park H K. J Ind Eng Chem, 2013, 19: 73
13. [13]
  [13] Centeno M A, Malet P, Carrizosa I, Odriozola J A. J Phys Chem B, 2000, 104: 3310
14. [14]
  [14] Lietti L, Nova I, Forzatti P. Top Catal, 2000, 11-12: 111
15. [15]
  [15] Lietti L, Nova I, Ramis G, Dall'Acqua L, Busca G, Giamello E, Forzatti P, Bregani F. J Catal, 1999, 187: 419
16. [16]
  [16] Du X S, Gao X, Fu Y C, Gao F, Luo Z Y, Cen K F. J Colloid Interface Sci, 2012, 368: 406
17. [17]
  [17] Li Q, Yang H S, Nie A M, Fan X Y, Zhang X B. Catal Lett, 2011, 141: 1237
18. [18]
  [18] Putluru S S R, Riisager A, Fehrmann R. Catal Lett, 2009, 133: 370
19. [19]
  [19] Gao R H, Zhang D S, Liu X G, Shi L Y, Maitarad P, Li H R, Zhang J P, Cao W G. Catal Sci Technol, 2013, 3: 191
20. [20]
  [20] Lee K J, Kumar P A, Maqbool M S, Rao K N, Song K H, Ha H P. Appl Catal B, 2013, 142-143: 705
21. [21]
  [21] Lee K J, Maqbool M S, Kumar P A, Song K H, Ha H P. Catal Lett, 2013, 143: 988
22. [22]
  [22] Ettireddy P R, Ettireddy N, Mamedov S, Boolchand P, Smirniotis P G. Appl Catal B, 2007, 76: 123
23. [23]
  [23] Vargas M A L, Casanova M, Trovarelli A, Busca G. Appl Catal B, 2007, 75: 303
24. [24]
  [24] Boningari T, Koirala R, Smirniotis P G. Appl Catal B, 2012, 127: 255
25. [25]
  [25] Sagar A, Trovarelli A, Casanova M, Schermanz K. SAE Int J Engines, 2011, 4: 1839
26. [26]
  [26] Yang S J, Wang C Z, Ma L, Peng Y, Qu Z, Yan N Q, Chen J H, Chang H Z, Li J H. Catal Sci Technol, 2013, 3: 161
27. [27]
  [27] Liu Z M, Li Y, Zhu T L, Su H, Zhu J Z. Ind Eng Chem Res, 2014, 53: 12964
28. [28]
  [28] Huang L, Shi L Y, Zhao X, Xu J, Li H R, Zhang J P, Zhang D S. CrystEngComm, 2014, 16: 5128
29. [29]
  [29] Liu F D, He H, Lian Z H, Shan W P, Xie L J, Asakura K, Yang W W, Deng H. J Catal, 2013, 307: 340
30. [30]
  [30] Casanova M, Schermanz K, Llorca J, Trovarelli A. Catal Today, 2012, 184: 227
31. [31]
  [31] Park E, Kim M, Jung H, Chin S, Jurng J. ACS Catal, 2013, 3: 1518
32. [32]
  [32] Zhang J, Xu Q, Li M J, Feng Z C, Li C. J Phys Chem C, 2009, 113: 1698
33. [33]
  [33] Zhang J, Xu Q, Feng Z C, Li M J, Li C. Angew Chem Int Ed, 2008, 47: 1766
34. [34]
  [34] Gao X T, Jehng J M, Wachs I E. J Catal, 2002, 209: 43
35. [35]
  [35] Giakoumelou I, Fountzoula C, Kordulis C, Boghosian S. J Catal, 2006, 239: 1
36. [36]
  [36] Besselmann S, Löffler E, Muhler M. J Mol Catal A, 2000, 162: 401
37. [37]
  [37] Huang L, Zhao X, Zhang L, Shi L Y, Zhang J P, Zhang D S. Nanoscale, 2015, 7: 2743
38. [38]
  [38] Li K R, Wang Y J, Wang S R, Zhu B L, Zhang S M, Huang W P, Wu S H. J Nat Gas Chem, 2009, 18: 449
39. [39]
  [39] Huo C L, Ouyang J, Yang H M. Sci Rep, 2014, 4: 3682
40. [40]
  [40] Zhao W, Zhong Q, Pan Y X, Zhang R. Chem Eng J, 2013, 228: 815
41. [41]
  [41] Zhao Y B, Qin Z F, Wang G F, Dong M, Huang L C, Wu Z W, Fan W B, Wang J G. Fuel, 2013, 104: 22
42. [42]
  [42] Chen S, Chu W, Liu X, Tong D G. J Nat Gas Chem, 2011, 20: 553
43. [43]
  [43] Liu F D, He H, Zhang C B, Feng Z C, Zheng L R, Xie Y N, Hu T D. Appl Catal B, 2010, 96: 408
44. [44]
  [44] Trawczyński J, Bielak B, Miśta W. Appl Catal B, 2005, 55: 277
45. [45]
  [45] Zheng J, Chu W, Zhang H, Jiang C F, Dai X Y. J Nat Gas Chem, 2010, 19: 583
46. [46]
  [46] Li C M, Zhou J Y, Gao W, Zhao J W, Liu J, Zhao Y F, Wei M, Evans D G, Duan X. J Mater Chem A, 2013, 1: 5370
47. [47]
  [47] Palacio L A, Silva J M, Ribeiro F R, Ribeiro M F. Catal Today, 2008, 133-135: 502
48. [48]
  [48] Nguyen L D, Loridant S, Launay H, Pigamo A, Dubois J L, Millet J M M. J Catal, 2006, 237: 38
49. [49]
  [49] Chary K V R, Kumar C P, Rajiah T, Srikanth C S. J Mol Catal A, 2006, 258: 313
50. [50]
  [50] Palacio L A, Silva E R, Catalão R, Silva J M, Hoyos D A, Ribeiro F R, Ribeiro M F. J Hazard Mater, 2008, 153: 628
51. [51]
  [51] Casanova M, Schermanz K, Llorca J, Trovarelli A. Catal Today, 2012, 184: 227
52. [52]
  [52] Cai S X, Zhang D S, Zhang L, Huang L, Li H R, Gao R H, Shi L Y, Zhang J P. Catal Sci Technol, 2014, 4: 93
53. [53]
  [53] Fang C, Zhang D S, Shi L Y, Gao R H, Li H R, Ye L P, Zhang J P. Catal Sci Technol, 2013, 3: 803
54. [54]
  [54] Zhang D S, Zhang L, Shi L Y, Fang C, Li H R, Gao R H, Huang L, Zhang J P. Nanoscale, 2013, 5: 1127
55. [55]
  [55] Zhang L, Zhang D S, Zhang J P, Ca i S X, Fang C, Huang L, Li H R, Gao R H, Shi L Y. Nanoscale, 2013, 5: 9821
56. [56]
  [56] Fang C, Zhang D S, Cai S X, Zhang L, Huang L, Li H R, Maitarad P, Shi L Y, Gao R H, Zhang J P. Nanoscale, 2013, 5: 9199
57. [57]
  [57] Shan W P, Liu F D, He H, Shi X Y, Zhang C B. Catal Today, 2012, 184: 160
58. [58]
  [58] Shan W P, Liu F D, He H, Shi X Y, Zhang C B. Appl Catal B, 2012, 115-116: 100
59. [59]
  [59] Tronconi E, Nova I, Ciardelli C, Chatterjee D, Weibel M. J Catal, 2007, 245: 1
60. [60]
  [60] Koebel M, Madia G, Raimondi F, Wokaun A. J Catal, 2002, 209: 159
61. [61]
  [61] Schwidder M, Heikens S, De Toni A, Geisler S, Berndt M, Brückner A, Grünert W. J Catal, 2008, 259: 96
62. [62]
  [62] Shi X Y, Liu F D, Xie L J, Shan W P, He H. Environ Sci Technol, 2013, 47: 3293
63. [63]
  [63] Liu F D, Asakura K, He H, Liu Y C, Shan W P, Shi X Y, Zhang C B. Catal Today, 2011, 164: 520
64. [64]
  [64] Long R Q, Yang R T. J Catal, 2002, 207: 158
65. [65]
  [65] Cheng L S, Yang R T, Chen N. J Catal, 1996, 164: 70
66. [66]
  [66] Liu F D, He H. J Phys Chem C, 2010, 114: 16929
67. [67]
  [67] Chmielarz L, Dziembaj R, Grzybek T, Klinik J, Łojewski T, Olszewska D, Węgrzyn A. Catal Lett, 2000, 70: 51
68. [68]
  [68] Wu Z B, Jiang B Q, Liu Y, Wang H Q, Jin R B. Environ Sci Technol, 2007, 41: 5812
69. [69]
  [69] Chen L, Li J H, Ge M F. Environ Sci Technol, 2010, 44: 9590
70. [70]
  [70] Peng Y, Wang C Z, Li J H. Appl Catal B, 2014, 144: 538
71. [71]
  [71] Zhu J, Gao F, Dong L H, Yu W J, Qi L, Wang Z, Dong L, Chen Y. Appl Catal B, 2010, 95: 144
72. [72]
  [72] Gu T T, Jin R B, Liu Y, Liu H F, Weng X L, Wu Z B. Appl Catal B, 2013, 129: 30
73. [73]
  [73] Liu F D, He H, Ding Y, Zhang C B. Appl Catal B, 2009, 93: 194
74. [74]
  [74] Larrubia M A, Ramis G, Busca G. Appl Catal B, 2001, 30: 101
75. [75]
  [75] Qi G, Yang R T, Chang R. Appl Catal B, 2004, 51: 93
76. [76]
  [76] Long R Q, Yang R T. J Catal, 2002, 207: 224
77. [77]
  [77] Zhou G Y, Zhong B C, Wang W H, Guan X J, Huang B C, Ye D Q, Wu H J. Catal Today, 2011, 175: 157
78. [78]
  [78] Foo R, Vazhnova T, Lukyanov D B, Millington P, Collier J, Rajaram R, Golunski S. Appl Catal B, 2015, 162: 174
79. [79]
  [79] Burkardt A, Weisweiler W, van den Tillaart J A A, Schäfer- Sindlinger A, Lox E S. Top Catal, 2001, 16-17: 369
80. [80]
  [80] Si Z C, Weng D, Wu X D, Li J, Li G. J Catal, 2010, 271: 43
81. [81]
  [81] Zhang Q L, Song Z X, Ning P, Liu X, Li H, Gu J J. Catal Commun, 2015, 59: 170
1. [1]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
2. [2]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
3. [3]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
4. [4]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
5. [5]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
6. [6]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
7. [7]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
8. [8]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
9. [9]
  Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . 原子精确的(AgPd)₂₇团簇用于硝酸盐电还原制氨：一种配体诱导策略来调控金属核. Acta Physico-Chimica Sinica, 2025, 41(1): 2403008-. doi: 10.3866/PKU.WHXB202403008
10. [10]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
11. [11]
  Xinyu Miao , Hao Yang , Jie He , Jing Wang , Zhiliang Jin . 调整Keggin型多金属氧酸盐电子结构构建S型异质结用于光催化析氢. Acta Physico-Chimica Sinica, 2025, 41(6): 100051-. doi: 10.1016/j.actphy.2025.100051
12. [12]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
13. [13]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
14. [14]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
15. [15]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
16. [16]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
17. [17]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
18. [18]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
19. [19]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
20. [20]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(601)
HTML views(81)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Highly dispersed V2O5/TiO2 modified with transition metals (Cu, Fe, Mn, Co) as efficient catalysts for the selective reduction of NO with NH3

Metrics

通讯作者: 陈斌, bchen63@163.com

Highly dispersed V₂O₅/TiO₂ modified with transition metals (Cu, Fe, Mn, Co) as efficient catalysts for the selective reduction of NO with NH₃