Citation: Yanyan Xu, Mingming Gao, Guohui Zhang, Xinhua Wang, Jiajia Li, Shuguang Wang, Yuanhua Sang. Electrochemically reduced graphene oxide with enhanced electrocatalytic activity toward tetracycline detection[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1936-1942. doi: 10.1016/S1872-2067(15)60956-1 shu

Electrochemically reduced graphene oxide with enhanced electrocatalytic activity toward tetracycline detection

1.
a Shandong Provincial Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Jinan 250100, Shandong, China;

Corresponding author: Mingming Gao, Shuguang Wang,
Received Date: 23 April 2015
Available Online: 3 July 2015
Fund Project: 国家自然科学基金(21007033) (21007033) 山东大学基本科研业务费专项资金(2015JC017). (2015JC017)

An electrochemically reduced graphene oxide sample, ERGO_-0.8V, was prepared by electrochemical reduction of graphene oxide (GO) at -0.8 V, which shows unique electrocatalytic activity toward tetracycline (TTC) detection compared to the ERGO_-1.2V (GO applied to a negative potential of -1.2 V), GO, chemically reduced GO (CRGO)-modified glassy carbon electrode (GC) and bare GC electrodes. The redox peaks of TTC on an ERGO_-0.8V-modified glass carbon electrode (GC/ERGO_-0.8V) were within 0-0.5 V in a pH 3.0 buffer solution with the oxidation peak current correlating well with TTC concentration over a wide range from 0.1 to 160 mg/L. Physical characterizations with Fourier transform infrared (FT-IR), Raman, and X-ray photoelectron spectroscopies (XPS) demonstrated that the oxygen-containing functional groups on GO diminished after the electrochemical reduction at -0.8 V, yet still existed in large amounts, and the defect density changed as new sp² domains were formed. These changes demonstrated that this adjustment in the number of oxygen-containing groups might be the main factor affecting the electrocatalytic behavior of ERGO. Additionally, the defect density and sp² domains also exert a profound influence on this behavior. A possible mechanism for the TTC redox reaction at the GC/ERGO_-0.8V electrode is also presented. This work suggests that the electrochemical reduction is an effective method to establish new catalytic activities of GO by setting appropriate parameters.
- Electrochemically reduced graphene oxide,
- Electrochemical detection,
- Tetracycline,
- Electrocatalytic activity,
- Oxygen-containing functional groups
1. [1]
  [1] Richardson B J, Lam P K S, Martin M. Marine Pollut Bull, 2005, 50: 913
2. [2]
  [2] Pruden A, Pei R, Storteboom H, Carlson K H. Environ Sci Technol, 2006, 40: 7445
3. [3]
  [3] Oka H, Ito Y, Matsumoto H. J Chromatogr A, 2000, 882: 109
4. [4]
  [4] Schenck F J, Callery P S. J Chromatogr A, 1998, 812: 99
5. [5]
  [5] Zhou M, Wang Y L, Zhai Y M, Zhai J F, Ren W, Wang F, Dong S J. Chemi Eur J, 2009, 15: 6116
6. [6]
  [6] Guo H L, Wang X F, Qian Q Y, Wang F B, Xia X H. ACS Nano, 2009, 3: 2653
7. [7]
  [7] Loetanantawong B, Suracheep C, Somasundrum M, Surareungchai W. Anal Chem, 2004, 76: 2266
8. [8]
  [8] Vega D, Agüí L, González-Cortés A, Yáñez-Sedeño P, Pingarrón J M. Anal Bioanal Chem, 2007, 389: 951
9. [9]
  [9] Oungpipat W, Southwell-Keely P, Alexander P W. Analyst, 1995, 120: 1559
10. [10]
  [10] Guo G P, Zhao F Q, Xiao F, Zeng B G. Int J Electrochem Sci, 2009, 4: 1365
11. [11]
  [11] Wang H T, Zhao H M, Quan X, Chen S. Electroanalysis, 2011, 23: 1863
12. [12]
  [12] Shao Y Y, Wang J, Wu H, Liu J, Aksay I A, Lin Y H. Electroanalysis, 2010, 22: 1027
13. [13]
  [13] Gao W, Alemany L B, Ci L J, Ajayan P M. Nat Chem, 2009, 1: 403
14. [14]
  [14] Loh K P, Bao Q L, Eda G, Chhowalla M. Nat Chem, 2010, 2: 1015
15. [15]
  [15] Zhu C Z, Dong S J. Nanoscale, 2013, 5: 1753
16. [16]
  [16] Ambrosi A, Bonanni A, Sofer Z, Cross J S, Pumera M. Chem Eur J, 2011, 17: 10763
17. [17]
  [17] Wang J F, Yang S L, Guo D Y, Yu P, Li D, Ye J S, Mao L Q. Electrochem Commun, 2009, 11: 1892
18. [18]
  [18] Shao Y Y, Wang J, Engelhard M, Wang C M, Lin Y H. J Mater Chem, 2010, 20: 743
19. [19]
  [19] Ramesha G K, Sampath S. J Phy Chem C, 2009, 113: 7985
20. [20]
  [20] Xu X B, Huang D K, Cao K, Wang M K, Zakeeruddin S M, Grätzel M. Sci Rep, 2013, 3: 1489
21. [21]
  [21] Yang T, Li X, Li Q H, Guo X H, Guan Q, Jiao K. Polym Chem, 2013, 4: 1228
22. [22]
  [22] Yuan B Q, Zeng X Y, Xu C Y, Liu L, Ma Y H, Zhang D J, Fan Y. Sensors Actuat B, 2013, 184: 15
23. [23]
  [23] Zhang D J, Xu C Y, Li S J, Zhang R C, Yan H L, Miao H J, Fan Y, Yuan B Q. J Electroanal Chem, 2014, 717-718: 219
24. [24]
  [24] Pumera M. Chem Soc Rev, 2010, 39: 4146
25. [25]
  [25] Alwarappan S, Erdem A, Liu C, Li C Z. J Phy Chem C, 2009, 113: 8853
26. [26]
  [26] Zeng Q, Cheng J S, Tang L H, Liu X F, Liu Y Z, Li J H, Jiang J H. Adv Funct Mater, 2010, 20: 3366
27. [27]
  [27] Zhou Y F, Zhang G Q, Chen J, Yuan G E, Xu L, Liu L F, Yang F L. Electrochem Commun, 2012, 22: 69
28. [28]
  [28] Stankovich S, Dikin D A, Piner R D, Kohlhaas K A, Kleinhammes A, Jia Y Y, Wu Y, Nguyen S T, Ruoff R S. Carbon, 2007, 45: 1558
29. [29]
  [29] Noel M, Anantharaman P N. Surf Coatings Technol, 1986, 28: 161
30. [30]
  [30] Hallam P M, Banks C E. Electrochem Commun, 2011, 13: 8
31. [31]
  [31] Murphy M A, Wilcox G D, Dahm R H, Marken F. Electrochem Commun, 2003, 5: 51
32. [32]
  [32] Kang X H, Wang J, Wu H, Liu J, Aksay I A, Lin Y H. Talanta, 2010, 81: 754
1. [1]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
2. [2]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
3. [3]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
4. [4]
  Rui LIU , Xinjun ZHOU , Tao WANG . Photocatalytic degradation performance of tetracycline by MOF-74-Mn/g-C₃N₄ Z-type heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1796-1804. doi: 10.11862/CJIC.20250033
5. [5]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
6. [6]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
7. [7]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
8. [8]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
9. [9]
  Ziyang Long , Quanzheng Li , Chengliang Zhang , Haifeng Shi . BiVO₄/WO_3-x S-scheme heterojunctions with amplified internal electric field for boosting photothermal-catalytic activity. Acta Physico-Chimica Sinica, 2025, 41(10): 100122-0. doi: 10.1016/j.actphy.2025.100122
10. [10]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . Rationally Designed ZnFe_1.2Co_0.8O₄/BiVO₄ S-Scheme Heterojunction with Spin-Polarization for the Elimination of Antibiotic. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-0. doi: 10.1016/j.actphy.2025.100050
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
12. [12]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
13. [13]
  Lutian Zhao , Yangge Guo , Liuxuan Luo , Xiaohui Yan , Shuiyun Shen , Junliang Zhang . Electrochemical Synthesis for Metallic Nanocrystal Electrocatalysts: Principle, Application and Challenge. Acta Physico-Chimica Sinica, 2024, 40(7): 2306029-0. doi: 10.3866/PKU.WHXB202306029
14. [14]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
15. [15]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
16. [16]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008
17. [17]
  Yuanyuan JIANG , Fangfang TU , Yuhong ZHANG , Shi CHEN , Jiayuan XIANG , Xinhui XIA . Preparation and electrochemical properties of high-stability cathode prelithiation additive. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1101-1111. doi: 10.11862/CJIC.20240441
18. [18]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
19. [19]
  Yuanyuan Ping , Wangqing Kong . 光催化碳氢键官能团化合成1-苯基-1,2-乙二醇. University Chemistry, 2025, 40(6): 238-247. doi: 10.12461/PKU.DXHX202408092
20. [20]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . Electrochemical CO₂ Reduction to C₂₊ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-0. doi: 10.3866/PKU.WHXB202404012

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(671)
HTML views(61)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142