Citation: Teng Xue, Huaping Liu, Yimeng Wang, Haihong Wu, Peng Wu, Mingyuan He. Seed-induced synthesis of small-crystal TS-1 using ammonia as alkali source[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1928-1935. doi: 10.1016/S1872-2067(15)60955-X shu

Seed-induced synthesis of small-crystal TS-1 using ammonia as alkali source

1.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China

Corresponding author: Haihong Wu,
Received Date: 9 June 2015
Available Online: 14 July 2015
Fund Project: 国家自然科学基金(21403070, 21373088) (21403070, 21373088) 上海市教育委员会科研创新项目(13zz038) (13zz038) 上海市科委“创新行动计划”基础研究重点项目(12JC1403600) (12JC1403600) 国家科技支撑计划(2012BAE05B02) (2012BAE05B02) 上海市重点学科项目(B409). (B409)

Small-crystal TS-1 was synthesized via a seed-induced approach using ammonia as the alkali source and tetrapropylammonium bromide as an auxiliary structure-directing agent. The TS-1 samples were characterized using X-ray diffraction, N₂ adsorption-desorption, Fourier-transform infrared spectroscopy, inductively coupled plasma atomic emission spectroscopy, scanning electron microscopy, and ultraviolet-visible spectroscopy. The use of the colloidal seed reduced the crystal size, and an appropriate amount of silicalite-1 seed assisted Ti incorporation into the TS-1 framework. This method reduces the cost of TS-1 synthesis because a significantly smaller amount of tetrapropylammonium hydroxide is used. The catalytic performance of the synthesized small-crystal TS-1 samples in cyclohexanone ammoximation was better than that of bulk TS-1 as a result of improved diffusion and a larger number of active tetrahedral Ti centers.
- Small crystal,
- TS-1 molecular sieve,
- Seed-induced synthesis,
- Ammonia,
- Catalytic oxidation,
- Cyclohexanone ammoximation
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