Citation: Siping Jian, Yingwei Li. Ni@Pd core-shell nanoparticles supported on a metal-organic framework as highly efficient catalysts for nitroarenes reduction[J]. Chinese Journal of Catalysis, ;2016, 37(1): 91-97. doi: 10.1016/S1872-2067(15)60940-8 shu

Ni@Pd core-shell nanoparticles supported on a metal-organic framework as highly efficient catalysts for nitroarenes reduction

Siping Jian ,
Yingwei Li ^,

1.
State Key Laboratory of Pulp and Paper Engineering, School of Chemistry and Chemical Engineering, South China University of Technology, Guanzhou 510640, Guangdong, China;

Corresponding author: Yingwei Li,
Received Date: 7 June 2015
Available Online: 19 June 2015
Fund Project: 国家自然科学基金(21322606, 21436005) (21322606, 21436005) 高等学校博士学科点专项科研基金(20120172110012) (20120172110012) 广东省自然科学基金(S2011020002397, 2013B090500027). (S2011020002397, 2013B090500027)

Ni@Pd core-shell nanoparticles with a mean particle size of 8-9 nm were prepared by solvothermal reduction of bivalent nickel and palladium in oleylamine and trioctylphosphine. Subsequently, the first-ever deposition of Ni@Pd core-shell nanoparticles having different compositions on a metal-organic framework (MIL-101) was accomplished by wet impregnation in n-hexane. The Ni@Pd/MIL-101 materials were characterized by powder X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, and energy-dispersive X-ray spectroscopy and also investigated as catalysts for the hydrogenation of nitrobenzene under mild reaction conditions. At 30 ℃ and 0.1 MPa of H₂ pressure, the Ni@Pd/MIL-101 gives a TOF as high as 375 h^-1 for the hydrogenation of nitrobenzene and is applicable to a wide range of substituted nitroarenes. The exceptional performance of this catalyst is believed to result from the significant Ni-Pd interaction in the core-shell structure, together with promotion of the conversions of aromatics by uncoordinated Lewis acidic Cr sites on the MIL-101 support.
- Nickel,
- Palladium,
- Core-shell nanoparticle,
- Metal-organic framework,
- Nitroarene,
- Hydrogenation,
- Heterogeneous catalysis
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