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Citation: Huan Li, Guangxu Chen, Paul N. Duchesne, Peng Zhang, Yan Dai, Huayan Yang, Binghui Wu, Shengjie Liu, Chaofa Xu, Nanfeng Zheng. A nanoparticulate polyacetylene-supported Pd(Ⅱ) catalyst combining the advantages of homogeneous and heterogeneous catalysts[J]. Chinese Journal of Catalysis, ;2015, 36(9): 1560-1572. doi: 10.1016/S1872-2067(15)60930-5 shu

A nanoparticulate polyacetylene-supported Pd(Ⅱ) catalyst combining the advantages of homogeneous and heterogeneous catalysts

Huan Li ^a,b,, ,
Guangxu Chen ^a ,
Paul N. Duchesne ^c ,
Peng Zhang ^c ,
Yan Dai ^a ,
Huayan Yang ^a ,
Binghui Wu ^a ,
Shengjie Liu ^a ,
Chaofa Xu ^a ,
Nanfeng Zheng ^a,,

1.
a State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;

Corresponding author: Huan Li, Nanfeng Zheng,
Received Date: 26 April 2015
Available Online: 5 June 2015
Fund Project: 科技部纳米研究国家重大科学研究计划(2011CB932403, 2015CB932303) (2011CB932403, 2015CB932303) 国家自然科学基金(221420102001, 21131005, 21390390, 21333008). (221420102001, 21131005, 21390390, 21333008)

A novel nanoparticulate polyacetylene-supported Pd(Ⅱ) catalyst (NP-Pd(Ⅱ)) for use in the aqueous Suzuki-Miyaura cross coupling reaction was successfully synthesized by simply treating an aqueous solution of PdCl₄^2- with acetylene under ambient conditions. Electron microscopy, Fourier transform infrared spectroscopy, Raman spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy and X-ray absorption spectroscopy were employed to characterize the NP-Pd(Ⅱ) structure in detail. These analyses demonstrated that the Pd atoms in the NP-Pd(Ⅱ) were present as Pd(Ⅱ) and were coordinated with both the Cl atoms and the C=C bonds of the polyacetylene. Both the homogeneous distribution of the Pd(Ⅱ) along the polyacetylene backbone and the aggregation of the NP-Pd(Ⅱ) in solution work in conjunction to make this material an ideal catalyst, combining the advantages of both homogeneous and heterogeneous catalysts.
- Suzuki coupling,
- Acetylene,
- Palladium complex,
- Aqueous reaction
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