Citation: Bingsen Zhang, Aiguo Zheng, Xiaoli Pan, Yiming Niu, Xiaoxin Zhang, Dangsheng Su, Baoning Zong. Microstructure of rapidly quenched Ni-Al based catalysts by advanced electron microscopy[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1662-1667. doi: 10.1016/S1872-2067(15)60925-1 shu

Microstructure of rapidly quenched Ni-Al based catalysts by advanced electron microscopy

1.
a Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, Liaoning, China;

Corresponding author: Dangsheng Su, Baoning Zong,
Received Date: 3 April 2015
Available Online: 3 June 2015
Fund Project: 石油化工催化材料与反应工程国家重点实验室(中国石油化工股份有限公司石油化工科学研究院)开放基金 (中国石油化工股份有限公司石油化工科学研究院)

The microstructure of air-sensitive Raney-type catalysts directly determines their activity and selectivity for a catalytic reaction. The fine structure of a rapidly quenched Ni-Al alloy doped with Fe and Cr (RQ Ni-Al-FC) was investigated by electron microscopy imaging and spectroscopic techniques, and its structure was successfully characterized by using a vacuum transfer holder in the transmission electron microscope. The microstructural comparison of pristine and passivated/combusted samples was discussed in detail. This work provides the structure of RQ Ni-Al based catalysts as a contribution to exploring their synthesis-structure-performance relationship.
- Nickel-aluminum based catalyst,
- Electron microscopy,
- Spectroscopy,
- Vacuum transfer holder,
- Microstructure
1. [1]
  [1] Zong B N. Catal Surv Asia, 2007, 11: 87
2. [2]
  [2] Zong B N, Mu X H, Zhang X X, Meng X K, Qiao M H. Chin J Catal (宗保宁, 慕旭宏, 张晓昕, 孟祥堃, 乔明华. 催化学报), 2013, 34: 828
3. [3]
  [3] Meng X K, Mu X H, Zong B N, Min E Z, Zhu Z H, Fu S B, Luo Y B. Catal Today, 2003, 79-80: 21
4. [4]
  [4] Liu B, Qiao M H, Deng J F, Fan K N, Zhang X X, Zong B N. J Catal, 2001, 204: 512
5. [5]
  [5] Hu H R, Qiao M H, Pei Y, Fan K N, Li H X, Zong B N, Zhang X X. Appl Catal A, 2003, 252: 173
6. [6]
  [6] Hu H R, Qiao M H, Wang S, Fan K N, Li H X, Zong B N, Zhang X X. J Catal, 2004, 221: 612
7. [7]
  [7] Hu H R, Xie F Z, Pei Y, Qiao M H, Yan S R, He H Y, Fan K N, Li H X, Zong B N, Zhang X X. J Catal, 2006, 237: 143
8. [8]
  [8] Sun B, Lin J, Xu K, Pei Y, Yan S R, Qiao M H, Zhang X X, Zong B N. ChemCatChem, 2013, 5: 3857
9. [9]
  [9] Luo G, Yan S R, Qiao M H, Zhang K, Hu H R, He H Y, Fan K N. Chem Res Chin Univ, 2004, 20: 452
10. [10]
  [10] Mu X H, Zong B N, Min E Z, Wang X, Wang Y, Zhang X X, Shu X T. US Patent 6368996. 2002
11. [11]
  [11] Zhang X X, Zong B N, Min E Z. ACS Div Petrol Chem Prepr, 2002, 47: 387
12. [12]
  [12] Xie F Z, Chu X W, Hu H R, Qiao M H, Yan S R, Zhu Y L, He H Y, Fan K N, Li H X, Zong B N, Zhang X X. J Catal, 2006, 241: 211
13. [13]
  [13] Wang W Y, Yang Y Q, Luo H A, Liu W Y. Catal Commun, 2010, 11: 803
14. [14]
  [14] Devred F, Hoffer B W, Sloof W G, Kooyman P J, van Langeveld A D, Zandbergen H W. Appl Catal A, 2003, 244: 291
15. [15]
  [15] Lei H, Song Z, Tan D L, Bao X H, Mu X H, Zong B N, Min E Z. Appl Catal A, 2001, 214: 69
16. [16]
  [16] Hu H R, Qiao M H, Xie F Z, Fan K N, Lei H, Tan D L, Bao X H, Lin H L, Zong B N, Zhang X X. J Phys Chem B, 2005, 109: 5186
17. [17]
  [17] Potapov P L, Kulkova S E, Schryvers D, Verbeeck J. Phys Rev B, 2001, 64: 184110
18. [18]
  [18] Potapov P L, Kulkova S E, Schryvers D. J Microsc, 2003, 210: 102
19. [19]
  [19] Feldhoff A, Martynczuk J, Arnold M, Myndyk M, Bergmann I, Sepelak V, Gruner W, Vogt U, Hahnel A, Woltersdorf J. J Solid State Chem, 2009, 182: 2961
20. [20]
  [20] McBride S P, Brydson R. J Mater Sci, 2004, 39: 6723
21. [21]
  [21] Wang C M, Baer D R, Amonette J E, Engelhard M H, Antony J, Qiang Y. J Am Chem Soc, 2009, 131: 8824
22. [22]
  [22] Colliex C, Manoubi T, Ortiz C. Phys Rev B, 1991, 44: 11402
23. [23]
  [23] Wang H J, Gu X J, Poon S J, Shiflet G J. Phys Rev B, 2008, 77: 014204
24. [24]
  [24] Zong B N, Meng X K, Lin H L, Zhang X X, Mu X H, Min E Z. US Patent 6875340. 2005
1. [1]
  Qiaoqiao BAI , Anqi ZHOU , Xiaowei LI , Tang LIU , Song LIU . Construction of pressure-temperature dual-functional flexible sensors and applications in biomedicine. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2259-2274. doi: 10.11862/CJIC.20240128
2. [2]
  Yufan ZHAO , Jinglin YOU , Shixiang WANG , Guopeng LIU , Xiang XIA , Yingfang XIE , Meiqin SHENG , Feiyan XU , Kai TANG , Liming LU . Raman spectroscopic quantitative study of the melt microstructure in binary Li₂O-GeO₂ functional crystals. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1533-1544. doi: 10.11862/CJIC.20250063
3. [3]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
4. [4]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
5. [5]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
6. [6]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
7. [7]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 2406012-0. doi: 10.3866/PKU.WHXB202406012
8. [8]
  Yuqiao Zhou , Weidi Cao , Shunxi Dong , Lili Lin , Xiaohua Liu . Study on the Teaching Reformation of Practical X-ray Crystallography. University Chemistry, 2024, 39(3): 23-28. doi: 10.3866/PKU.DXHX202303003
9. [9]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
10. [10]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
11. [11]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-0. doi: 10.3866/PKU.WHXB202406020
12. [12]
  Qiying Xia , Guokui Liu , Yunzhi Li , Yaoyao Wei , Xia Leng , Guangli Zhou , Aixiang Wang , Congcong Mi , Dengxue Ma . Construction and Practice of “Teaching-Learning-Assessment Integration” Model Based on Outcome Orientation: Taking “Structural Chemistry” as an Example. University Chemistry, 2024, 39(10): 361-368. doi: 10.3866/PKU.DXHX202311007
13. [13]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
14. [14]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-0. doi: 10.1016/j.actphy.2024.100044
15. [15]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
16. [16]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
17. [17]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
18. [18]
  Huiwei Ding , Bo Peng , Zhihao Wang , Qiaofeng Han . Advances in Metal or Nonmetal Modification of Bismuth-Based Photocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2305048-0. doi: 10.3866/PKU.WHXB202305048
19. [19]
  Yushan Cai , Fang-Xing Xiao . Revisiting MXenes-based Photocatalysis Landscape: Progress, Challenges, and Future Perspectives. Acta Physico-Chimica Sinica, 2024, 40(8): 2306048-0. doi: 10.3866/PKU.WHXB202306048
20. [20]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(632)
HTML views(40)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142