Citation: Liping Zheng, Shuixin Xia, Xiuyang Lu, Zhaoyin Hou. Transesterification of glycerol with dimethyl carbonate over calcined Ca-Al hydrocalumite[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1759-1765. doi: 10.1016/S1872-2067(15)60915-9 shu

Transesterification of glycerol with dimethyl carbonate over calcined Ca-Al hydrocalumite

1.
a Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028, Zhejiang, China;

Corresponding author: Zhaoyin Hou,
Received Date: 23 March 2015
Available Online: 16 May 2015
Fund Project: 国家自然科学基金(21473155, 21273198, 21073159) (21473155, 21273198, 21073159) 浙江省自然科学基金(LZ12B03001). (LZ12B03001)

A series of Ca-Al hydrocalumite with different Ca/Al ratios (1-6) were synthesized and used in the transesterification of glycerol with dimethyl carbonate (DMC) to glycerol carbonate (GC) under mild conditions. The calcined Ca-Al hydrocalumites were active with a selectivity toward GC that reached 97% at 93% conversion of glycerol over the sample with Ca/Al = 2 at 70 ℃, 3 h, and DMC/glycerol = 3. The glycerol conversion depended mainly on the proportion of strong basic sites in the calcined Ca-Al catalysts. The Ca₁₂Al₁₄O₃₃ phase in the calcined catalysts was stable, but CaO was lost in recycle experiments and thus brought deactivation.
- Glycerol,
- Dimethyl carbonate,
- Transesterification,
- Glycerol carbonate,
- Calcium-aluminum hydrocalumite
1. [1]
  [1] Pagliaro M, Ciriminna R, Kimura H, Rossi M, Della Pina C. Angew Chem Int Ed, 2007, 46: 4434
2. [2]
  [2] Zhou C H, Beltramini J N, Fan Y X, Lu G Q. Chem Soc Rev, 2008, 37: 527
3. [3]
  [3] Bozell J J, Petersen G R. Green Chem, 2010, 12: 539
4. [4]
  [4] Ide M S, Davis R J. Acc Chem Res, 2014, 47: 825
5. [5]
  [5] Maris E P, Ketchie W C, Murayama M, Davis R J. J Catal, 2007, 251: 281
6. [6]
  [6] Vasiliadou E S, Eggenhuisen T M, Munnik P, de Jongh P E, de Jong K P, Lemonidou A A. Appl Catal B, 2014, 145: 108
7. [7]
  [7] Nakagawa Y, Tomishige K. Catal Sci Technol, 2011, 1: 179
8. [8]
  [8] Wang S, Liu H C. Catal Lett, 2007, 117: 62
9. [9]
  [9] Maris E P, Davis R J. J Catal, 2007, 249: 328
10. [10]
  [10] Huang Z W, Cui F, Kang H X, Chen J, Zhang X Z, Xia C G. Chem Mater, 2008, 20: 5090
11. [11]
  [11] Zope B N, Hibbitts D D, Neurock M, Davis R J. Science, 2010, 330: 74
12. [12]
  [12] Nie R F, Liang D, Shen L, Gao J, Chen P, Hou Z Y. Appl Catal B, 2012, 127: 212
13. [13]
  [13] Liu S S, Sun K Q, Xu B Q. ACS Catal, 2014, 4: 2226
14. [14]
  [14] Katryniok B, Paul S, Dumeignil F. ACS Catal, 2013, 3: 1819
15. [15]
  [15] Chai S H, Wang H P, Liang Y, Xu B Q. J Catal, 2007, 250: 342
16. [16]
  [16] Chai S H, Wang H P, Liang Y, Xu B Q. Green Chem, 2007, 9: 1130
17. [17]
  [17] Takagaki A, Iwatani K, Nishimura S, Ebitani K. Green Chem, 2010, 12: 578
18. [18]
  [18] Liu P, Derchi M, Hensen E J M. Appl Catal A, 2013, 467: 124
19. [19]
  [19] Liu P, Derchi M, Hensen E J M. Appl Catal B, 2014, 144: 135
20. [20]
  [20] Sonnati M O, Amigoni S, Taffin de Givenchy E P, Darmanin T, Choulet O, Guittard F. Green Chem, 2013, 15: 283
21. [21]
  [21] Shaikh A A G, Sivaram S. Chem Rev, 1996, 96: 951
22. [22]
  [22] Vieville C, Yoo J W, Pelet S, Mouloungui Z. Catal Lett, 1998, 56: 245
23. [23]
  [23] Aresta M, Dibenedetto A, Nocito F, Pastore C. J Mol Catal A, 2006, 257: 149
24. [24]
  [24] Hammond C, Lopez-Sanchez J A, Ab Rahim M H, Dimitratos N, Jenkins R L, Carley A F, He Q, Kiely C J, Knight D W, Hutchings G J. Dalton Trans, 2011, 40: 3927
25. [25]
  [25] Wang L G, Ma Y B, Wang Y, Liu S M, Deng Y Q. Catal Commun, 2011, 12: 1458
26. [26]
  [26] Kim D W, Park K A, Kim M J, Kang D H, Yang J G, Park D W. Appl Catal A, 2014, 473: 31
27. [27]
  [27] Zhang J, He D H. React Kinet, Mech Catal, 2014, 113: 375
28. [28]
  [28] Jagadeeswaraiah K, Kumar C R, Prasad P S S, Loridant S, Lingaiah N. Appl Catal A, 2014, 469: 165
29. [29]
  [29] Li H G, Gao D Z, Gao P, Wang F, Zhao N, Xiao F K, Wei W, Sun Y H. Catal Sci Technol, 2013, 3: 2801
30. [30]
  [30] Zhang J, He D H. J Colloid Interf Sci, 2014, 419: 31
31. [31]
  [31] Rokicki G, Rakoczy P, Parzuchowski P, Sobiecki M. Green Chem, 2005, 7: 529
32. [32]
  [32] Ochoa-Gomez J R, Gomez-Jimenez-Aberasturi O, Maestro-Madurga B, Pesquera-Rodriguez A, Ramirez-Lopez C, Lorenzo-Ibarreta L, Torrecilla-Soria J, Villaran-Velasco M C. Appl Catal A, 2009, 366: 315
33. [33]
  [33] Algoufi Y T, Hameed B H. Fuel Process Technol, 2014, 126: 5
34. [34]
  [34] Parameswaram G, Srinivas M, Hari Babu B, Sai Prasad P S, Lingaiah N. Catal Sci Technol, 2013, 3: 3242
35. [35]
  [35] Malyaadri M, Jagadeeswaraiah K, Prasad P S S, Lingaiah N. Appl Catal A, 2011, 401: 153
36. [36]
  [36] Zheng L P, Xia S X, Hou Z T, Zhang M Y, Hou Z Y. Chin J Catal (郑丽萍, 夏水鑫, 侯召同, 张梦媛, 侯昭胤. 催化学报), 2014, 35: 310
37. [37]
  [37] Pan S Y, Zheng L P, Nie R F, Xia S X, Chen P, Hou Z Y. Chin J Catal (潘赛勇, 郑丽萍, 聂仁峰, 夏水鑫, 陈平, 侯昭胤. 催化学报), 2012, 33: 1772
38. [38]
  [38] Pfeiffer H, Ávalos-Rendón T, Lima E, Valente J S. J Environ Eng, 2011, 137: 1058
39. [39]
  [39] Cavani F, Trifirò F, Vaccari A. Catal Today, 1991, 11: 173
40. [40]
  [40] Chang P H, Lee T J, Chang Y P, Chen S Y. ChemSusChem, 2013, 6: 1076
41. [41]
  [41] Gao L J, Teng G Y, Xiao G M, Wei R P. Biomass Bioenergy, 2010, 34: 1283
42. [42]
  [42] Kuwahara Y, Tsuji K, Ohmichi T, Kamegawa T, Mori K, Yamashita H. Catal Sci Technol, 2012, 2: 1842
43. [43]
  [43] Zhou J Z, Xu Z P, Qiao S Z, Liu J Y, Liu Q, Xu Y F, Zhang J, Qian G R. Appl Clay Sci, 2011, 54: 196
44. [44]
  [44] Wang Q, Gao Y S, Zhang Z, Duan L H, Umar A, O'Hare D. Sci Adv Mater, 2013, 5: 411
45. [45]
  [45] Zhang P, Qian G R, Shi H S, Ruan X X, Yang J, Frost R L. J Colloid Interf Sci, 2012, 365: 110
46. [46]
  [46] Lv T F, Ma W, Xin G, Wang R, Xu J, Liu D M, Liu F J, Pan D C. J Hazard Mater, 2012, 237-238: 121
47. [47]
  [47] Zhang J, Xu Y F, Qian G R, Xu Z P, Chen C, Liu Q. J Phy Chem C, 2010, 114: 10768
48. [48]
  [48] Alvarez M G, Segarra A M, Contreras S, Sueiras J E, Medina F, Figureueras F. Chem Eng J, 2010, 161: 340
49. [49]
  [49] Yuan Z L, Wang L N, Wang J H, Xia S X, Chen P, Hou Z Y, Zheng X M. Appl Catal B, 2011, 101: 431
50. [50]
  [50] Martavaltzi C S, Lemonidou A A. Ind Eng Chem Res, 2008, 47: 9537
51. [51]
  [51] Simanjuntak F S H, Kim T K, Lee S D, Ahn B S, Kim H S, Lee H. Appl Catal A, 2011, 401: 220
1. [1]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
2. [2]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
3. [3]
  Yinwu Su , Xuanwen Zheng , Jianghui Du , Boda Li , Tao Wang , Zhiyan Huang . Green Synthesis of 1,3-Dibromoacetone Using Halogen Exchange Method: Recommending a Basic Organic Synthesis Teaching Experiment. University Chemistry, 2024, 39(5): 307-314. doi: 10.3866/PKU.DXHX202311092
4. [4]
  Changyan Sun , Hualei Zhou , Bin Dong . Application of “PBL” Teaching Mode in Inorganic Chemistry Experimental Education in the Perspective of Course Ideology and Politics: Taking Preparation of Manganese Carbonate as an Example. University Chemistry, 2024, 39(11): 378-383. doi: 10.12461/PKU.DXHX202402016
5. [5]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
6. [6]
  Shuying Zhu , Shuting Wu , Ou Zheng . Improvement and Expansion of the Experiment for Determining the Rate Constant of the Saponification Reaction of Ethyl Acetate. University Chemistry, 2024, 39(4): 107-113. doi: 10.3866/PKU.DXHX202310117
7. [7]
  Ruitong Zhang , Zhiqiang Zeng , Xiaoguang Zhang . Improvement of Ethyl Acetate Saponification Reaction and Iodine Clock Reaction Experiments. University Chemistry, 2024, 39(8): 197-203. doi: 10.3866/PKU.DXHX202312004
8. [8]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
9. [9]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
10. [10]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
11. [11]
  Yifeng TAN , Ping CAO , Kai MA , Jingtong LI , Yuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO₃/SiO₂. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147
12. [12]
  Jiaojiao Yu , Bo Sun , Na Li , Cong Wen , Wei Li . Improvement of Classical Organic Experiment Based on the “Reverse-Step Optimization Method”: Taking Synthesis of Ethyl Acetate as an Example. University Chemistry, 2025, 40(3): 333-341. doi: 10.12461/PKU.DXHX202405177
13. [13]
  Yanan Jiang , Yuchen Ma . Brief Discussion on the Electronic Exchange Interaction in Quantum Chemistry Computations. University Chemistry, 2025, 40(3): 10-15. doi: 10.12461/PKU.DXHX202402058
14. [14]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
15. [15]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
16. [16]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
17. [17]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
18. [18]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
19. [19]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
20. [20]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(363)
HTML views(37)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142