Citation: Teng Fu, Pei Hu, Tao Wang, Zhen Dong, Nianhua Xue, Luming Peng, Xuefeng Guo, Weiping Ding. High selectivity to p-chloroaniline in the hydrogenation of p-chloronitrobenzene on Ni modified carbon nitride catalyst[J]. Chinese Journal of Catalysis, ;2015, 36(11): 2030-2035. doi: 10.1016/S1872-2067(15)60904-4 shu

High selectivity to p-chloroaniline in the hydrogenation of p-chloronitrobenzene on Ni modified carbon nitride catalyst

1.
Key Laboratory of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, Jiangsu, China

Corresponding author: Weiping Ding,
Received Date: 10 April 2015
Available Online: 16 May 2015

A nanocomposite composed of Ni modified carbon nitride was synthesized and used in the hydrogenation of p-chloronitrobenzene. H/D exchange demonstrated that the hydrogen chemisorbed on the surface of this nanocomposite catalyst had a hydrogen atom density of 0.65/nm². It was active for hydrogenation but its activity was inferior to the hydrogen adsorbed on a Ni/Al₂O₃ catalyst. Catalytic tests showed that this catalyst possessed a lower activity than Ni/Al₂O₃ but the selectivity towards p-chloroaniline was above 99.9%. Even at high conversion, the catalyst maintained high selectivity, which was attributed to the unique surface property of the catalyst and the absence of a site for the adsorption of p-chloronitrobenzene, which prevents the C-Cl bond from breaking.
- Hydrogenation,
- p-Chloronitrobenzene,
- Carbon nitride,
- Nickel,
- Selectivity
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