Citation: Zhao Liu, Yan Gao, Ze Yu, Min Zhang, Jianhui Liu. Effects of Br substituent on catalytic performance of Ru-bda (H2bda = 2,2'-bipyridine-6,6'-dicarboxylic acid) catalysts for water oxidation[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1742-1749. doi: 10.1016/S1872-2067(15)60895-6 shu

Effects of Br substituent on catalytic performance of Ru-bda (H2bda = 2,2'-bipyridine-6,6'-dicarboxylic acid) catalysts for water oxidation

1.
Institute of Artificial photosynthesis, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, Liaoning, China

Corresponding author: Yan Gao, Jianhui Liu,
Received Date: 8 April 2015
Available Online: 18 May 2015
Fund Project: 国家自然科学基金(20923006, 21120102036, 21106015和91233201) (20923006, 21120102036, 21106015和91233201) 国家重点基础研究发展计划(973计划, 2014CB239402) (973计划, 2014CB239402) 中央高校基本科研业务专项基金(DUT13RC(3)103, DUT15LK08). (DUT13RC(3)103, DUT15LK08)

A series of new Ru-bda catalysts with Br modification on the equatorial ligand, [Ru(Ln)(picoline)₂] (H₂L1 = 4-Br-2,2'-bipyridine-6,6'-dicarboxylic acid (4-Br-bda), 2; H₂L2 = 4,4'-diBr-bda, 3) and [Ru(L1)(isoquinoline)₂] 5, were synthesized for catalytic water oxidation. Compared with the un-substituted catalysts, the catalysts modified with Br displayed a marked change in the catalytic activities and reaction orders. The results confirm that the electronic effect of Br has a large effect on the kinetics and leads to the change in reaction orders.
- Water oxidation,
- Ruthenium-bda catalyst,
- Bromine modification,
- Electronic effect,
- Kinetic studies
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