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Citation: Kai Gong, Hualan Wang, Shuxin Wang, Ying Wang, Jinghua Chen. Efficient synthesis of 1,8-dioxo-octahydroxanthenes catalyzed by β-cyclodextrin grafted with butyl sulfonic acid in aqueous media[J]. Chinese Journal of Catalysis, ;2015, 36(8): 1249-1255. doi: 10.1016/S1872-2067(15)60888-9 shu

Efficient synthesis of 1,8-dioxo-octahydroxanthenes catalyzed by β-cyclodextrin grafted with butyl sulfonic acid in aqueous media

1.
a School of Pharmaceutical Science, Jiangnan University, Wuxi 214122, Jiangsu, China;

Corresponding author: Kai Gong,
Received Date: 7 April 2015
Available Online: 9 May 2015
Fund Project: 国家自然科学基金(51303069) (51303069) 江南大学自主科研基金(JUSRP11236). (JUSRP11236)

β-Cyclodextrin was functionalized with butyl sulfonic acid to give an efficient, eco-friendly catalyst for the synthesis of 1,8-dioxo-octahydroxanthenes via the one-pot condensation of aromatic aldehydes and active methylene carbonyl compounds in aqueous media. This new methodology offers several advantages such as excellent yields, short reaction time, a simple procedure and mild reaction conditions. Furthermore, the catalyst can be readily recovered and reused up to five times without a significant loss in its activity.
- One-pot synthesis,
- Acidic catalyst,
- β-Cyclodextrin bearing butyl sulfonic acid,
- 1,8-Dioxo-octahydroxanthenes,
- Aqueous media
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