Citation: Chin-Te Hung, Zih-Hao Liou, Pitchaimani Veerakumar, Pei-Hao Wu, Tuan-Chi Liu, Shang-Bin Liu. Ordered mesoporous carbon supported bifunctional PtM (M = Ru, Fe, Mo) electrocatalysts for a fuel cell anode[J]. Chinese Journal of Catalysis, ;2016, 37(1): 43-53. doi: 10.1016/S1872-2067(15)60878-6 shu

Ordered mesoporous carbon supported bifunctional PtM (M = Ru, Fe, Mo) electrocatalysts for a fuel cell anode

1.
a Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan, China;
2.
b Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan, China;
3.
c Department of Chemistry, National Taiwan Normal University, Taipei 11677, Taiwan, China

Corresponding author: Tuan-Chi Liu, Shang-Bin Liu,
Received Date: 30 March 2015
Available Online: 27 April 2015
Fund Project: 台湾科技支撑项目(NSC98-2113-M-001-017-MY3, NSC101-2113-M-001-020-MY3). (NSC98-2113-M-001-017-MY3, NSC101-2113-M-001-020-MY3)

The deposition onto an ordered mesoporous carbon (OMC) support of well dispersed PtM (M = Ru, Fe, Mo) alloy nanoparticles (NPs) were synthesized by a direct replication method using SBA-15 as the hard template, furfuryl alcohol and trimethylbeneze as the primary carbon sources, and metal acetylacetonate as the alloying metal precursor and secondary carbon source. The physicochemical properties of the PtM-OMC catalysts were characterized by N₂ adsorption-desorption, X-ray diffraction, transmission electron microscopy, X-ray absorption near edge structure, and extended X-ray absorption fine structure. The alloy PtM NPs have an average size of 2-3 nm and were well dispersed in the pore channels of the OMC support. The second metal (M) in the PtM NPs was mostly in the reduced state, and formed a typical core (Pt)-shell (M) structure. Cyclic voltammetry measurements showed that these PtM-OMC electrodes had excellent electrocatalytic activities and tolerance to CO poisoning during the methanol oxidation reaction, which surpassed those of typical activated carbon-supported PtRu catalysts. In particular, the PtFe-OMC catalyst, which exhibited the best performance, can be a practical anodic electrocatalyst in direct methanol fuel cells due to its superior stability, excellent CO tolerance, and low production cost.
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