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Citation: Chenglong Zou, Guanyu Sha, Yao Huang, Guoxing Niu, Dongyuan Zhao. Incorporation of Al3+ ions to promote the stabilization effect of (NH4)2SiF6 treatment on the hydrothermal stability of mesoporous SBA-15 zeolite[J]. Chinese Journal of Catalysis, ;2015, 36(7): 1001-1008. doi: 10.1016/S1872-2067(15)60855-5 shu

Incorporation of Al3+ ions to promote the stabilization effect of (NH4)2SiF6 treatment on the hydrothermal stability of mesoporous SBA-15 zeolite

  • 1.

    a Department of Chemistry, Fudan University, Shanghai 200433, China;

  • Corresponding author: Guoxing Niu, 
  • Received Date: 8 February 2015
    Available Online: 25 March 2015

    Fund Project: 国家重点基础研究发展计划(973计划, 2010CB226901, 2013CB934100) (973计划, 2010CB226901, 2013CB934100) 国家自然科学基金(U1463206). (U1463206)

  • This work demonstrates an improved (NH4)2SiF6 treatment to enhance the hydrothermal stability of mesoporous SBA-15 zeolite. In this treatment, Al3+ ions are incorporated into SBA-15 zeolite first, then it is treated with 5% (NH4)2SiF6 solution according to 1% SiO2 of SBA-15 and finally washed with HCl (2 mol/L) to remove the pre-incorporated Al3+ ions. The obtained SBA-15 exhibits higher hydrothermal stability than that without pre-incorporated Al3+. Compared with the latter, the sample maintains a better ordered mesostructure and a larger surface area (271 m2/g) after hydrothermal treatment at 800 ℃ for 12 h in 100% steam. The results show that incorporating Al3+ ions into SBA-15 zeolite before (NH4)2SiF6 treatment obviously promotes the stabilization effect of (NH4)2SiF6 treatment. The mechanism suggests that the incorporated Al3+ ions can effectively capture F- ions that have been released from (NH4)2SiF6, and thus reduce their etching into the SBA-15 zeolite framework. This ensures that the positive factors of (NH4)2SiF6 treatment, such as silicon insertion and surface hydrophobization by F- ions, play effective roles in the improvement of the hydrothermal stability of SBA-15 zeolite. This promoting effect of the Al3+ ions is closely related to the method that is used to introduce the Al3+ and the SBA-15 zeolite processing temperature.
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    1. [1]

      [1] Klimova T E, Valencia D, Mendoza-Nieto J A, Hernandez-Hipolito P. J Catal, 2013, 304: 29

    2. [2]

      [2] Parlett C M A, Keshwalla P, Wainwright S G, Bruce D W, Hondow N S, Wilson K, Lee A F. ACS Catal, 2013, 3: 2122

    3. [3]

      [3] Valencia D, Klimova T. Appl Catal B, 2013, 129: 137

    4. [4]

      [4] Nakazawa J, Smith B J, Stack T D P. J Am Chem Soc, 2012, 134: 2750

    5. [5]

      [5] Jia L X, Sun X Y, Ye X Q, Zou C L, Gu H F, Huang Y, Niu G X, Zhao D Y. Microporous Mesoporous Mater, 2013, 176: 16

    6. [6]

      [6] Liu H M, Li Y M, Wu H, Yang W W, He D H. Chin J Catal (刘会敏, 李宇明, 吴昊, 杨维维, 贺德华. 催化学报), 2014, 35: 1520

    7. [7]

      [7] Song M J, Zou C L, Niu G X, Zhao D Y. Chin J Catal (宋明娟, 邹成龙, 牛国兴, 赵东元. 催化学报), 2012, 33: 140

    8. [8]

      [8] Du Y C, Lan X J, Liu S, Ji Y Y, Zhang Y L, Zhang W P, Xiao F S. Microporous Mesoporous Mater, 2008, 112: 225

    9. [9]

      [9] Xiao F S. Top Catal, 2005, 35: 9

    10. [10]

      [10] Pham H N, Anderson A E, Johnson R L, Schmidt-Rohr K, Datye A K. Angew Chem Int Ed, 2012, 51: 13163

    11. [11]

      [11] Li C L, Wang Y Q, Guo Y L, Liu X H, Guo Y, Zhang Z G, Wang Y S, Lu G Z. Chem Mater, 2007, 19: 173

    12. [12]

      [12] Bernardoni F, Fadeev A Y. J Colloid Interface Sci, 2011, 356: 690

    13. [13]

      [13] Herbert R, Wang D, Schomäcker R, Schlögl R, Hess C. ChemPhysChem, 2009, 10: 2230

    14. [14]

      [14] Zhao Y X, Gao C G, Li Y X, Zhang T M. Microporous Mesoporous Mater, 2009, 124: 42

    15. [15]

      [15] Chen G D, Wang L Z, Lei J Y, Zhang J L. Microporous Mesoporous Mater, 2009, 124: 204

    16. [16]

      [16] Jiang T L, Tao H X, Ren J W, Liu X H, Wang Y Q, Lu G Z. Microporous Mesoporous Mater, 2011, 142: 341

    17. [17]

      [17] Wang L Z, Shao Y F, Zhang J L, Anpo M. Microporous Mesoporous Mater, 2007, 100: 241

    18. [18]

      [18] Du Y C, Lan X J, Liu S, Ji Y Y, Zhang Y L, Zhang W P, Xiao F S. Microporous Mesoporous Mater, 2008, 112: 225

    19. [19]

      [19] Pan D H, Yuan P, Zhao L Z, Liu N, Zhou L, Wei G F, Zhang J, Ling Y C, Fan Y, Wei B Y, Liu H Y, Yu C Z, Bao X J. Chem Mater, 2009, 21: 5413

    20. [20]

      [20] Zhang F Q, Yan Y, Yang H F, Meng Y, Yu C Z, Tu B, Zhao D Y. J Phys Chem B, 2005, 109: 8723

    21. [21]

      [21] Michaux F, Carteret C, Stébé M J, Blin J L. Microporous Mesoporous Mater, 2008, 116: 308

    22. [22]

      [22] Han Y, Li D F, Zhao L, Song J W, Yang X Y, Li N, Di Y, Li C J, Wu S, Xu X Z, Meng X J, Lin K F, Xiao F S. Angew Chem Int Ed, 2003, 42: 3633

    23. [23]

      [23] Galarneau A, Nader M, Guenneau F, Di Renzo F, Gedeon A. J Phys Chem C, 2007, 111: 8268

    24. [24]

      [24] Han Y, Li N, Zhao L, Li D F, Xu X Z, Wu S, Di Y, Li C J, Zou Y C, Yu Y, Xiao F S. J Phys Chem B, 2003, 107: 7551

    25. [25]

      [25] Guo W P, Li X, Zhao X S. Microporous Mesoporous Mater, 2006, 93: 285

    26. [26]

      [26] Pu H P, Han C Y, Wang H, Xu S W, Zhang L Y, Zhang Y Y, Luo Y M. Appl Surf Sci, 2012, 258: 8895

    27. [27]

      [27] Zhao D Y, Feng J L, Huo Q S, Melosh N, Frederickson G H, Chmelka B F, Stucky G D. Science, 1998, 279: 548

    28. [28]

      [28] Li Q, Wu Z X, Tu B, Park S S, Ha C S, Zhao D Y. Microporous Mesoporous Mater, 2010, 135: 95

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