Citation: Tao Chang, Leqin He, Xiaojing Zhang, Mingxia Yuan, Shenjun Qin, Jiquan Zhao. Brönsted acid surfactant-combined dicationic ionic liquids as green catalysts for biodiesel synthesis from free fatty acids and alcohols[J]. Chinese Journal of Catalysis, ;2015, 36(7): 982-986. doi: 10.1016/S1872-2067(15)60852-X shu

Brönsted acid surfactant-combined dicationic ionic liquids as green catalysts for biodiesel synthesis from free fatty acids and alcohols

Tao Chang ^a ,
Leqin He ^a,b ,
Xiaojing Zhang ^a ,
Mingxia Yuan ^a ,
Shenjun Qin ^a,, ,
Jiquan Zhao ^b,,

1.
a Key Laboratory for Resource Exploration Research of Hebei Province, Hebei University of Engineering, Handan 056038, Hebei, China;

Corresponding author: Shenjun Qin, Jiquan Zhao,
Received Date: 29 January 2015
Available Online: 27 March 2015
Fund Project: 河北省自然科学基金(B2012402001, D2014402046) (B2012402001, D2014402046) 河北省高校百名优秀创新人才支持计划(BR2-204) (BR2-204) 河北省高校科学技术基金(Q2012030). (Q2012030)

Quaternary ammonium Brönsted acid surfactant-combined dicationic ionic liquids (BASDILs) based on zwitterionic 1,2-bis[N-methyl-N-(3-sulfopropyl)-alkylammonium]ethane betaines and various anions were prepared and characterized. BASDILs possess properties similar to those of phase-separated catalysts and were applied to the catalytic synthesis of biodiesel from free fatty acids and alcohols. Several factors were investigated and the results indicated that [C₁₂Sb][p-CH₃C₆H₄SO₃] was the optimal catalyst, with good catalytic performance and reusability under mild conditions.
- Biodiesel,
- Esterification,
- Brönsted acidity,
- Surfactant-combined dicationic ionic,
- liquid
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