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Citation: Qianli Zhang, Xinyan Guo, Xiaodan Cao, Dongtian Wang, Jie Wei. Facile preparation of a Ti/α-PbO2/β-PbO2 electrode for theelectrochemical degradation of 2-chlorophenol[J]. Chinese Journal of Catalysis, ;2015, 36(7): 975-981. doi: 10.1016/S1872-2067(15)60851-8 shu

Facile preparation of a Ti/α-PbO2/β-PbO2 electrode for theelectrochemical degradation of 2-chlorophenol

  • 1.

    College of Chemistry and Material Engineering, Jiangsu Key Laboratory for Environment Functional Materials, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu, China

  • Corresponding author: Jie Wei, 
  • Received Date: 8 January 2015
    Available Online: 27 March 2015

    Fund Project: 国家自然科学基金(251178283, 20905055) (251178283, 20905055) 江苏省研究生创新工程(SJLX_0580). (SJLX_0580)

  • A Ti/α-PbO2/β-PbO2 electrode with high stability was prepared and examined toward the electrochemical degradation of 2-chlorophenol. Scanning electron microscopy analysis revealed that Ti/α-PbO2/β-PbO2 had a cauliflower morphology comprising small β-PbO2 crystals. The 2-chlorophenol removal rate using the Ti/α-PbO2/β-PbO2 electrode was 100% after 180 min of electrolysis under optimal conditions, which were selected based on the orthogonal test method, i.e., initial concentration of 2-cholorophenol = 50 mg/L, concentration of Na2SO4 = 0.1 mol/L, temperature = 35 ℃, and anode current density = 20 mA/cm2. Kinetic analyses demonstrated that the electrochemical oxidation of 2-chlorophenol on the Ti/α-PbO2/β-PbO2 electrode followed pseudo-first order kinetics.
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    1. [1]

      [1] Wei M C, Tian D, Liu S, Zheng X L, Duan S, Zhou C L. Sensor Actuat B, 2014, 195: 452

    2. [2]

      [2] Teng W, Li X Y, Zhao Q D, Chen G H. J Mater Chem A, 2013, 1: 9060

    3. [3]

      [3] He Z Q, Wang C, Wang H Y, Hong F Y, Xu X H, Chen J M, Song S. J Hazard Mater, 2011, 189: 595

    4. [4]

      [4] Mayani S V, Mayani V J, Kim S W. Can J Chem Eng, 2013, 91: 1270

    5. [5]

      [5] Ortiz de la Plata G B, Alfano O M, Cassano A E. Appl Catal B, 2010, 95: 1

    6. [6]

      [6] Gong J J, Li D P, Huang J, Ding L Y, Tong Y L, Li K, Zhang C. Catal Lett, 2013, 144: 487

    7. [7]

      [7] Khanikar N, Bhattacharyya K G. Chem Eng J, 2013, 233: 88

    8. [8]

      [8] Yoon J H, Shim Y B, Lee B S, Choi S Y, Won M S. Bull Korean Chem Soc, 2012, 33: 2274

    9. [9]

      [9] Vallejo M, San Román M F, Ortiz I. Environ Sci Technol, 2013, 47: 12400

    10. [10]

      [10] Zheng Y H, Su W Q, Chen S Y, Wu X Z, Chen X M. Chem Eng J, 2011, 174: 304

    11. [11]

      [11] Martinez-Huitle C A, Ferro S. Chem Soc Rev, 2006, 35: 1324

    12. [12]

      [12] Zhao J, Zhu C Z, Lu J, Hu C J, Peng S C, Chen T H. Electrochim Acta, 2014, 118: 169

    13. [13]

      [13] Lin H, Niu J F, Xu J L, Li Y, Pan Y H. Electrochim Acta, 2013, 97: 167

    14. [14]

      [14] Song S, Zhan L Y, He Z Q, Lin L L, Tu J J, Zhang Z H, Chen J M, Xu L J. J Hazard Mater, 2010, 175: 614

    15. [15]

      [15] Weiss E, Groenen-Serrano K, Savall A. J Appl Electrochem, 2008, 38: 329

    16. [16]

      [16] Awad H S, Galwa N A. Chemosphere, 2005, 61: 1327

    17. [17]

      [17] Wang Y, Shen Z Y, Li Y, Niu J F. Chemosphere, 2010, 79: 987

    18. [18]

      [18] Vazquez-Gomez L, de Battisti A, Ferro S, Cerro M, Reyna S, Martínez-Huitle C A, Quiroz M A. Clean Soil, Air, Water, 2012, 40: 408

    19. [19]

      [19] Yahiaoui I, Aissani-Benissad F, Fourcade F, Amrane A. Environ Prog Sustain Energy, 2012, 31: 515

    20. [20]

      [20] Lin H, Niu J F, Ding S Y, Zhang L L. Water Res, 2012, 46: 2281

    21. [21]

      [21] Lin H, Niu J F, Xu J L, Huang H, Li D, Yue Z H, Feng C H. Environ Sci Technol, 2013, 47: 13039

    22. [22]

      [22] Niu J F, Lin H, Xu J L, Wu H, Li Y Y. Environ Sci Technol, 2012, 46: 10191

    23. [23]

      [23] Chen Z, Yu Q, Liao D H, Guo Z C, Wu J. Trans Nonferrous Met Soc China, 2013, 23: 1382

    24. [24]

      [24] Abaci S, Tamer U, Pekmez K, Yildiz A. Electrochim Acta, 2005, 50: 3655

    25. [25]

      [25] Aquino J M, Rocha-Filho R C, Ruotolo L A M, Bocchi N, Biaggio S R. Chem Eng J, 2014, 251: 138

    26. [26]

      [26] Aquino J M, Pereira G F, Rocha-Filho R C, Bocchi N, Biaggio S R. J Hazard Mater, 2011, 192: 1275

    27. [27]

      [27] Souza F L, Aquino J M, Irikura K, Miwa D W, Rodrigo M A, Motheo A J. Chemosphere, 2014, 109: 187

    28. [28]

      [28] Li G T, Qu J H, Zhang X W, Ge J T. Water Res, 2006, 40: 213

    29. [29]

      [29] Duan X Y, Ma F, Yuan Z X, Chang L M, Jin X T. J Taiwan Inst Chem Eng, 2013, 44: 95

    30. [30]

      [30] Li G T, Yip H Y, Wong K H, Hu C, Qu J H, Wong P K. J Environ Sci, 2011, 23: 998

    31. [31]

      [31] Mohd Y. J Sci Technol, 2011, 3: 109

    32. [32]

      [32] Wei L, Mao X H, Lin A, Gan F X. Russ J Electrochem, 2011, 47: 1394

    33. [33]

      [33] Li H Y, Chen Y, Zhang Y H, Han W Q, Sun X Y, Li J S, Wang L J. J Electroanal Chem, 2013, 689: 193

    34. [34]

      [34] Chen Y, Li H Y, Liu W J, Tu Y, Zhang Y H, Han W Q, Wang L J. Chemosphere, 2014, 113: 48

    35. [35]

      [35] Da Silva L M, De Faria L A, Boodts J F C. Electrochim Acta, 2003, 48: 699

    36. [36]

      [36] Wang Z Y, Qi J Y, Feng Y, Li K, Li X. J Ind Eng Chem, 2014, 20: 3672

    37. [37]

      [37] Wang H, Wang J L. Appl Catal B, 2009, 89: 111

    38. [38]

      [38] Cong Y Q, Wu Z C, Ye Q, Tan T E. J Zhejiang Univ Sci, 2004, 5: 180

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