Citation: Fu Yang, Shuying Gao, Cuirong Xiong, Haiqing Wang, Jin Chen, Yan Kong. Coordination of manganese porphyrins on amino-functionalized MCM-41 for heterogeneous catalysis of naphthalene hydroxylation[J]. Chinese Journal of Catalysis, ;2015, 36(7): 1035-1041. doi: 10.1016/S1872-2067(15)60836-1 shu

Coordination of manganese porphyrins on amino-functionalized MCM-41 for heterogeneous catalysis of naphthalene hydroxylation

1.
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Technology University, Nanjing 210009, Jiangsu, China

Corresponding author: Yan Kong,
Received Date: 9 January 2015
Available Online: 17 March 2015
Fund Project: 国家自然科学基金(21276125, 21476108). (21276125, 21476108)

The different amounts of [5,10,15,20-tetrakis-(pentafluorophenyl)porphyrin] manganese chloride (TF₂₀PPMnCl) were immobilized on amino-functionalized MCM-41 for catalysis of the hydroxylation of naphthalene. The samples were characterized by X-ray powder diffraction, N₂ adsorption/ desorption isotherms, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, diffuse reflectance ultraviolet-visible spectroscopy, thermogravimetric and differential scanning calorimetry, and inductively coupled plasma mass spectrometry. The results indicated that the manganese porphyrins were axially coordinated on amino-functionalized MCM-41. The prepared samples showed remarkable catalytic activity in the hydroxylation of naphthalene with meta-chloroperbenzoic acid as the oxidant. The catalyst could be reused several times without loss of its activity.
- Manganese porphyrin,
- Immobilization,
- Axial coordination,
- Naphthalene hydroxylation,
- Heterogeneous catalysis
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