Citation: Laxmikant D. Chavan, Sunil G. Shankarwar. KSF supported 10-molybdo-2-vanadophosphoric acid as an efficient and reusable catalyst for one-pot synthesis of 2,4,5-trisubstituted imidazole derivatives under solvent-free condition[J]. Chinese Journal of Catalysis, ;2015, 36(7): 1054-1059. doi: 10.1016/S1872-2067(15)60830-0 shu

KSF supported 10-molybdo-2-vanadophosphoric acid as an efficient and reusable catalyst for one-pot synthesis of 2,4,5-trisubstituted imidazole derivatives under solvent-free condition

Laxmikant D. Chavan ,
Sunil G. Shankarwar ^,

1.
Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431 004, M.S., India

Corresponding author: Sunil G. Shankarwar,
Received Date: 2 February 2015
Available Online: 4 March 2015

The one-pot three-component cyclocondensation has been developed involving the reaction of benzil with an aromatic aldehydes and ammonium acetate under thermal solvent-free conditions in the presence of a KSF supported 10-molybdo-2-vanadophosphoric acid catalyst. 10-Molybdo-2-vanadophosphoric acid was immobilized on KSF with a 20% loading, which showed the highest catalytic activity. The catalyst was fully characterized using FT-IR spectroscopy, thermal analysis, XRD and SEM analysis techniques. There are several distinct advantages to this protocol, including high yields, short reaction time, operational simplicity and a recyclable catalyst with a facile work-up procedure.
- 2,4,5-Trisubstituted imidazole,
- Heteropoly acid,
- 10-Molybdo-2-vanadophosphoric acid,
- KSF clay,
- Heterogeneous catalyst
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