Citation: Davood Habibi, Somayyeh Vakili. Nano-sized silica supported FeCl₃ as an efficient heterogeneous catalyst for the synthesis of 1, 2, 4-triazine derivatives[J]. Chinese Journal of Catalysis, ;2015, 36(4): 620-625. doi: 10.1016/S1872-2067(15)60829-4 shu

Nano-sized silica supported FeCl₃ as an efficient heterogeneous catalyst for the synthesis of 1, 2, 4-triazine derivatives

Davood Habibi ^, ,
Somayyeh Vakili

1.
Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, 6517838683, Hamedan, Iran

Corresponding author: Davood Habibi,
Received Date: 21 September 2014
Available Online: 19 December 2014

The one-pot synthesis of a series of 1,2,4-triazines from the reactions of semicarbazide or thiosemicarbazide with various α,β-dicarbonyl compounds under reflux conditions in a EtOH-H₂O (9:1) mixture as solvent and catalyzed by nano-sized silica supported FeCl₃ (FeCl₃@SiO₂) was investigated. The FeCl₃ content of the catalyst was measured by atomic absorption to get the adsorption capacity. The reactions gave high yields of the product and the catalyst was easily separated and reused for successive reaction runs without significant loss of activity.
- Nano-sized silica supported FeCl₃,
- Multicomponent reactions,
- 1,2,4-Triazines,
- α,β-Dicarbonyl compounds,
- Semicarbazide,
- Thiosemicarbazide
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沈阳化工大学材料科学与工程学院沈阳 110142

Nano-sized silica supported FeCl3 as an efficient heterogeneous catalyst for the synthesis of 1, 2, 4-triazine derivatives

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通讯作者: 陈斌, bchen63@163.com

Nano-sized silica supported FeCl₃ as an efficient heterogeneous catalyst for the synthesis of 1, 2, 4-triazine derivatives