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Citation: Ye Yuan, Zhimiao Wang, Hualiang An, Wei Xue, Yanji Wang. Oxidative carbonylation of phenol with a Pd-O/CeO2-nanotubecatalyst[J]. Chinese Journal of Catalysis, ;2015, 36(7): 1142-1154. doi: 10.1016/S1872-2067(14)60312-0 shu

Oxidative carbonylation of phenol with a Pd-O/CeO2-nanotubecatalyst

  • 1.

    Hebei Provincial Key Laboratory of Green Chemistry & High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

  • Corresponding author: Wei Xue,  Yanji Wang, 
  • Received Date: 22 December 2014
    Available Online: 7 February 2015

    Fund Project: 国家自然科学基金(21236001, 21176056, 21106031) (21236001, 21176056, 21106031) 河北省高校百名优秀创新人才支持计划(II)(BR2-208) (II)(BR2-208) 河北省自然科学基金(B2015202228). (B2015202228)

  • CeO2 nanotubes (CeO2-NT) were synthesized using carbon nanotubes as template by a liquid phase deposition and hydrothermal method. X-ray diffraction, transmission electron microscopy, and N2 adsorption-desorption were used to characterize the CeO2-NT. The wall of CeO2-NT was composed of small interconnected nanocrystallites ranging from 4 to 9 nm in size. The specific surface area of CeO2-NT was 108.8 m2/g with an outer diameter of 25 nm and length > 300 nm. Supported Pd catalyst, Pd-O/CeO2-NT, was prepared using CeO2-NT as the support. Temperature-programmed reduction analysis showed that the surface oxygen on Pd-O/CeO2-NT could be reduced at low temperature, therefore it showed high activity in the reaction. Pd-O/CeO2-NT was used as the catalyst for the oxidative carbonylation of phenol. It has better activity and DPC selectivity than Pd-O/CeO2-P, which was prepared by supporting Pd on zero dimensional CeO2 particles. Under the optimized conditions, phenol conversion was 67.7% with 93.3% DPC selectivity with Pd-O/CeO2-NT. However, its catalytic activity decreased when the catalyst was used for the second time. This was attributed to the destruction of the tubular structure of Pd-O/CeO2-NT and Pd leaching during the reaction.
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