Citation: Wenshan Zhao, Chengke Qu, Lili Yang, Yuanchen Cui. Chitosan- supported cinchonine as an efficient organocatalyst for direct asymmetric aldol reaction in water[J]. Chinese Journal of Catalysis, ;2015, 36(3): 367-371. doi: 10.1016/S1872-2067(14)60248-5 shu

Chitosan- supported cinchonine as an efficient organocatalyst for direct asymmetric aldol reaction in water

1.
a College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China;

Corresponding author: Yuanchen Cui,
Received Date: 4 September 2014
Available Online: 10 October 2014

Chitosan-supported succinic anhydride-cinchonine (CTS-SA-CN) was synthesized via a two-step route with succinic anhydride as the linker. The catalyst was used to promote the direct asymmetric aldol reaction between cyclohexanone and a variety of aromatic aldehydes in aqueous medium. Aldol adducts were obtained in excellent yields (up to 99%) and good enantioselectivities (up to 96% ee). The CTS-SA-CN catalyst was successfully recycled simply by filtration after use, and was reused 5 times without any significant loss of activity.
- Chitosan,
- Cinchonine,
- Supported catalyst,
- Direct asymmetric aldol reaction
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