Citation: Huanwang Jing, Xiaomei Wang, Yong Liu, Anqi Wang. Preparation of magnetic nanocomposites of solid acid catalysts and their applicability in esterification[J]. Chinese Journal of Catalysis, ;2015, 36(2): 244-251. doi: 10.1016/S1872-2067(14)60221-7 shu

Preparation of magnetic nanocomposites of solid acid catalysts and their applicability in esterification

1.
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 73000, Gansu, China

Corresponding author: Huanwang Jing,
Received Date: 18 June 2014
Available Online: 1 September 2014

Solid acid catalysts are superior to traditional liquid acids because they are noncorrosive, environmentally benign, and recyclable. In addition, nano-magnetic solid acid catalysts are preferable as they exhibit large specific surface areas together with good acidity and are also readily separated from the post-reaction mixture. Three component nano-magnetic solid catalysts TiO₂-Al₂O₃-Fe₃O₄ and CeO₂-Al₂O₃-Fe₃O₄ and a four component catalyst ZrO₂-Al₂O₃-CeO₂-Fe₃O₄ were synthesized by a co-precipitation method and were subsequently characterized by inductively coupled plasma-atomic emission spectroscopy, Brunauer-Emmett-Teller surface area analysis, X-ray diffraction, transmission electron microscopy, and thermal gravimetric analysis. Their catalytic activities were also evaluated in the esterification reaction of acetic acid with n-butanol. The results demonstrated that these rare earth-based magnetic nanocomposites exhibited good catalytic activity.
- Magnetic nanocomposite,
- Solid acid catalyst,
- Co-precipitation method,
- Esterification reaction
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沈阳化工大学材料科学与工程学院沈阳 110142