Citation: Hui Wu, Tao Peng, Zongkui Kou, Jian Zhang, Kun Cheng, Daping He, Mu Pan, Shichun Mu. Core-shell graphene@amorphous carbon composites supported platinum catalysts for oxygen reduction reaction[J]. Chinese Journal of Catalysis, ;2015, 36(4): 490-495. doi: 10.1016/S1872-2067(14)60211-4 shu

Core-shell graphene@amorphous carbon composites supported platinum catalysts for oxygen reduction reaction

1.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, Hubei, China

Corresponding author: Shichun Mu,
Received Date: 12 July 2014
Available Online: 22 August 2014
Fund Project: 国家自然科学基金(51372186) (51372186) 国家重点基础研究发展计划(973计划, 2012CB215504) (973计划, 2012CB215504) 湖北省自然基金重点项目(2013CFA082) (2013CFA082)

A core-shell graphene nanosheets (GNS) and amorphous carbon composite (GNS@a-C) was prepared by a chlorination method and used as a highly efficient catalyst support for oxygen reduction reaction. Herein, GNS as a shell, with excellent conductivity, high surface area, and corrosion resistance, served as a protecting coating to alleviate the degradation of amorphous carbon core. Platinum nanoparticles were homogeneously deposited on the carbon support (Pt/GNS@a-C) and showed a good catalytic activity and a higher electrochemical stability when compared with a commercial Pt/C catalyst. The mass activity of Pt/GNS@a-C catalyst was 0.121 A/mg, which was almost twice as high as that of Pt/C (0.064 A/mg). Moreover, Pt/GNS@a-C retained 51% of its initial electrochemical specific area after 4000 operating cycles when compared with Pt/C (33%). Thus, the prepared catalyst featured excellent electrochemical stability, showing promise for application in polymer electrolyte membrane fuel cells.
- Low-temperature fuel cell,
- Support,
- Core-shell structure,
- Oxygen reduction reaction
1. [1]
  [1] Kinoshita K. Carbon: Electrochemical and Physicochemical Properties. New York: wiley, 1988
2. [2]
  [2] Yu X W, Ye S Y. J Power Sources, 2007, 172: 133
3. [3]
  [3] Stevens D A, Hicks M T, Haugen G M, Dahn J R. J Electrochem Soc, 2005, 152: A2309
4. [4]
  [4] Shao Y Y, Yin G P, Zhang J, Gao Y Z. Electrochim Acta, 2006, 51: 5853
5. [5]
  [5] Coloma F, Sepulvedaescribano A, Rodriguezreinoso F. J Catal, 1995, 154:299
6. [6]
  [6] Bom D, Andrews R, Jacques D, Anthony J, Chen B, Meier M S, Selegue J P. Nano Lett, 2002, 2: 615
7. [7]
  [7] He C Z, Desai S, Brown G, Bollepalli S. Electrochem Soc interface, 2005, 14(3): 41
8. [8]
  [8] Geim A K, Novoselov K S. Nat Mater, 2007, 6: 183
9. [9]
  [9] Li D, Muller M B, Gilje S, Kaner R B, Wallace G G. Nat Nanotechnol, 2008, 3: 101
10. [10]
  [10] Stankovich S, Dikin D A, Dommett G H B, Kohlhaas K M, Zimney E J, Stach E A, Piner R D, Nguyen S T, Ruoff R S. Nature, 2006, 442: 282
11. [11]
  [11] He D P, Cheng K, Peng T, Pan M, Mu S C. J Mater Chem A, 2013, 1: 2126
12. [12]
  [12] Wu P, Lü H F, Peng T, He D P, Mu S C. Sci Rep, 2014, 4: 3968
13. [13]
  [13] Zhao X, Hayner C M, Kung M C, Kung H H. ACS Nano, 2011, 5: 8739
14. [14]
  [14] Rao C N R, Sood A K, Voggu R, Subrahmanyam K S. J Phys Chem Lett, 2010, 1: 572
15. [15]
  [15] Du X S, Yu Z Z, Dasari A, Ma J, Mo M S, Meng Y Z, Mai Y W. Chem Mater, 2008, 20: 2066
16. [16]
  [16] Zu S Z, Han B H. J Phys Chem C, 2009, 113: 13651
17. [17]
  [17] He D P, Kou Z K, Xiong Y L, Cheng K, Chen X, Pan M, Mu S C. Carbon, 2014, 66: 312
18. [18]
  [18] He D P, Cheng K, Li H G, Peng T, Xu F, Mu S C, Pan M. Langmuir, 2012, 28: 3979
19. [19]
  [19] Yang X Y, Dou X, Rouhanipour A, Zhi L J, Rader H J, Mullen K. J Am Chem Soc, 2008, 130: 4216
20. [20]
  [20] Fan Z J, Yan J, Zhi L J, Zhang Q, Wei T, Feng J, Zhang M L, Qian W Z, Wei F. Adv Mater, 2010, 22: 3723
21. [21]
  [21] Peng T, Lv H F, He D P, Pan M, Mu S. C. Sci Rep, 2013, 3: 1148
22. [22]
  [22] Peng T, Kou Z K, Wu H, Mu S C. Sci Rep, 2014, 4: 5494
23. [23]
  [23] Bullot J, Schmidt M P. Phys Status Solidi B, 1987, 143: 345
24. [24]
  [24] Morimoto A, Kataoka T, Kumeda M, Shimizu T. Philos Mag B, 1984, 50: 517
25. [25]
  [25] Schmidt T J, Gasteiger H A, Stäb G P, Urban P M, Kolb D M, Behm R J. J Electrochem Soc, 1998, 145: 2354
26. [26]
  [26] Colombi Ciacchi L, Pompe W, De Vita A. J Phys Chem B, 2003, 107: 1755
27. [27]
  [27] Lim B, Jiang M J, Camargo P H C, Cho E C, Tao J, Lu X M, Zhu Y M, Xia Y N. Science, 2009, 324: 1302
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