Citation: Kunbing Ouyang, Zhenfeng Xi. Pd-catalyzed cyclodimerization of alkenyl and aryl dibromides: Construction of dibenzo[a,e]cyclooctatetraenes[J]. Chinese Journal of Catalysis, ;2015, 36(1): 24-32. doi: 10.1016/S1872-2067(14)60201-1 shu

Pd-catalyzed cyclodimerization of alkenyl and aryl dibromides: Construction of dibenzo[a,e]cyclooctatetraenes

Kunbing Ouyang ^a,b ,
Zhenfeng Xi ^b,,

1.
a Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;

Corresponding author: Zhenfeng Xi,
Received Date: 30 June 2014
Available Online: 21 July 2014
Fund Project: 国家重点基础研究发展计划(973计划, 2012CB821600) (973计划, 2012CB821600) 国家自然科学基金(21132001). (21132001)

Cyclooctatetraenes, including dibenzocyclooctatetraenes, are structurally interesting compounds and are widely used in many areas. Therefore, the development of synthetic methods for such compounds has long been attractive. In this work, a Pd-catalyzed coupling reaction between alkenylbromides and arylbromides has been realized. Multi-substituted 1,4-dibromo-1,3-butadienes and o-bromo-2-(2-bromovinyl)benzenes underwent a Pd-catalyzed cyclodimerization reaction to afford the corresponding multi-substituted cyclooctatetraenes and dibenzo[a,e] cyclooctatetraenes, respectively, in high yields and with excellent regioselectivity.
- Dibromide,
- Cyclooctatetraene,
- Dibenzo[a,e]cyclooctatetraene,
- 1,4-Dibromo-1,3-butadiene,
- Homo-coupling,
- Palladium catalyst
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