Citation: Suitao Qi, Yingying Li, Jiaqi Yue, Hao Chen, Chunhai Yi, Bolun Yang. Hydrogen production from decalin dehydrogenation over Pt-Ni/C bimetallic catalysts[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1833-1839. doi: 10.1016/S1872-2067(14)60178-9 shu

Hydrogen production from decalin dehydrogenation over Pt-Ni/C bimetallic catalysts

1.
School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China

Corresponding author: Suitao Qi,
Received Date: 6 April 2014
Available Online: 23 May 2014
Fund Project: 国家自然科学基金(21006076) (21006076) 高等学校博士学科点专项科研基金(20110201130002) (20110201130002) 中央高校基本科研业务费专项基金(xjj2011062). (xjj2011062)

Pt-Ni bimetallic catalysts and the corresponding monometallic Pt catalysts supported on active carbon were prepared by incipient wetness impregnation and characterized by X-ray diffraction, N₂ adsorption, and NH₃-temperature programmed desorption. Their activities for decalin dehydrogenation were investigated at a superheated liquid film state in a batch reactor. The effects of temperature, impregnation sequence, and Pt/Ni molar ratio on the dehydrogenation activity and the naphthalene yield were investigated. The results show that the Pt-Ni bimetallic catalyst significantly enhanced hydrogen evolution compared with either Ni or Pt monometallic catalyst. The highest dehydrogenation conversion and naphthalene yield were obtained when the Pt/Ni molar ratio was 1:1 and Pt was impregnated first. The experimental results were correlated with density functional theory calculations of hydrogen binding energy (HBE) on different catalytic surfaces. The correlation confirmed that bimetallic surfaces with stronger HBEs had higher dehydrogenation activities.
- Platinum,
- Nickel,
- Bimetallic,
- Decalin,
- Dehydrogenation,
- Density functional theory
1. [1]
  [1] Eberle U, Felderhoff M, Schüth F. Angew Chem Int Ed, 2009, 48: 6608
2. [2]
  [2] David E. J Mater Process Technol, 2005, 162-163: 169
3. [3]
  [3] Biniwale R B, Rayalu S, Devott S, Ichikawa M. Int J Hydrogen Energy, 2008, 33: 360
4. [4]
  [4] Zhu G L, Yang B L. Progr Chem (朱刚利, 杨伯伦. 化学进展), 2009, 21: 2760
5. [5]
  [5] Ninomiya W, Tanabe Y, Sotowa K I, Yasukawa T, Sugiyama S. Res Chem Intermed, 2008, 34: 663
6. [6]
  [6] Pande J V, Shukla A, Biniwale R B. Int J Hydrogen Energy, 2012, 37: 6756
7. [7]
  [7] Kariya N, Fukuoka A, Ichikawa M. Appl Catal A, 2002, 233: 91
8. [8]
  [8] Saito Y, Aramaki K, Hodoshima S, Saito M, Shono A, Kuwano J, Otake K. Chem Eng Sci, 2008, 63: 4935
9. [9]
  [9] Wang Y G, Shah N, Huffman G P. Energy Fuels, 2004, 18: 1429
10. [10]
  [10] Tien P D, Satoh T, Miura M, Nomura M. Fuel Process Technol, 2008, 89: 415
11. [11]
  [11] Du J P, Zhao R H, Jiao G R. Int J Hydrogen Energy, 2013, 38: 5789
12. [12]
  [12] Chen A B, Zhang W P, Li X Y, Tan D L, Han X W, Bao X H. Catal Lett, 2007, 119: 159
13. [13]
  [13] Shukla A A, Gosavi P V, Pande J V, Kumar V P, Chary K V R, Biniwale R B. Int J Hydrogen Energy, 2010, 35: 4020
14. [14]
  [14] Shinohara C, Kawakami S, Moriga T, Hayashi H, Hodoshima S, Saito Y, Sugiyama S. Appl Catal A, 2004, 266: 251
15. [15]
  [15] Tien P D, Satoh T, Miura M, Nomura M. Energy Fuels, 2005, 19: 731
16. [16]
  [16] Tien P D, Satoh T, Miura M, Nomura M. Energy Fuels, 2005, 19: 2110
17. [17]
  [17] Wang Y G, Shah N, Huggins F E, Huffman G P. Energy Fuels, 2006, 20: 2612
18. [18]
  [18] Jiang N Z, Rao K S R, Jin M J, Park S E. Appl Catal A, 2012, 425-426: 62
19. [19]
  [19] Suttisawat Y, Horikoshi S, Sakai H, Abe M. Int J Hydrogen Energy, 2010, 35: 6179
20. [20]
  [20] Yolcular S, Olgun Ö. Catal Today, 2008, 138: 198
21. [21]
  [21] Nagaraja B M, Shin C H, Jung K D. Appl Catal A, 2013, 467: 211
22. [22]
  [22] Patil S P, Pande J V, Biniwale R B. Int J Hydrogen Energy, 2013, 38: 15233
23. [23]
  [23] Alhumaidan F, Tsakiris D, Cresswell D, Garforth A. Int J Hydrogen Energy, 2013, 38: 14010
24. [24]
  [24] Aboul-Fotouh S M K, Aboul-Gheit N A K. Chin J Catal (催化学报), 2012, 33: 697
25. [25]
  [25] Gao X F, Chen C L, Ren S Y, Zhang J, Su D S. Chin J Catal (高旭锋, 谌春林, 任士远, 张建, 苏党生. 催化学报), 2012, 33: 1069
26. [26]
  [26] Biniwale R B, Kariya N, Ichikawa M. Catal Lett, 2005, 105: 83
27. [27]
  [27] Qi S T, Yu W T, Lonergan W W, Yang B L, Chen J G. Chin J Catal (齐随涛, 俞伟婷, Lonergan W W, 杨伯伦, 陈经广. 催化学报), 2010, 31: 955
28. [28]
  [28] Qi S T, Yu W T, Lonergan W W, Yang B L, Chen J G. ChemCatChem, 2010, 2: 625
29. [29]
  [29] Chen J G, Qi S T, Humbert M P, Menning C A, Zhu Y X. Acta Phys-Chim Sin (陈经广, 齐随涛, Humbert M P, Menning C A, 朱月香. 物理化学学报), 2010, 26: 869
30. [30]
  [30] Chen J G, Menning C A, Zellner M B. Surf Sci Rep, 2008, 63: 201
31. [31]
  [31] Skoplyak O, Barteau M A, Chen J G. ChemSusChem, 2008, 1: 524
32. [32]
  [32] Hansgen D A, Vlachos D G, Chen J G. Nat Chem, 2010, 2: 484
33. [33]
  [33] Shu Y Y, Murillo L E, Bosco J P, Huang W, Frenkel A I, Chen J G. Appl Catal A, 2008, 339: 169
34. [34]
  [34] Lima F H B, Zhang J, Shao M H, Sasaki K, Vukmirovic M B, Ticianelli E A, Adzic R R. J Phys Chem C, 2007, 111: 404
1. [1]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
2. [2]
  Lele Feng , Xueying Bai , Jifeng Pang , Hongchen Cao , Xiaoyan Liu , Wenhao Luo , Xiaofeng Yang , Pengfei Wu , Mingyuan Zheng . Single-atom Pd boosted Cu catalysts for ethanol dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(9): 100100-0. doi: 10.1016/j.actphy.2025.100100
3. [3]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
4. [4]
  Weiheng Liu , Juhua Luo , Jiahuan Shi , Di Lan , Shuangshuang Mao , Yu Xie . Honeycomb-like BiCo@NC composites derived from bimetallic organic frameworks for high-efficiency electromagnetic wave absorption. Acta Physico-Chimica Sinica, 2026, 42(8): 100313-0. doi: 10.1016/j.actphy.2026.100313
5. [5]
  Xinwan Zhao , Yue Cao , Minjun Lei , Zhiliang Jin , Tsubaki Noritatsu . Constructing S-scheme heterojunctions by integrating covalent organic frameworks with transition metal sulfides for efficient noble-metal-free photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(12): 100152-0. doi: 10.1016/j.actphy.2025.100152
6. [6]
  Kaifu Zhang , Shan Gao , Bin Yang . Application of Theoretical Calculation with Fun Practice in Raman Spectroscopy Experimental Teaching. University Chemistry, 2025, 40(3): 62-67. doi: 10.12461/PKU.DXHX202404045
7. [7]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
8. [8]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, 2025, 40(3): 206-214. doi: 10.12461/PKU.DXHX202407022
9. [9]
  Tongqi Ye , Yanqing Wang , Qi Wang , Huaiping Cong , Xianghua Kong , Yuewen Ye . Reform of Classical Thermodynamics Curriculum from the Perspective of Computational Chemistry. University Chemistry, 2025, 40(7): 387-392. doi: 10.12461/PKU.DXHX202409128
10. [10]
  Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308015-0. doi: 10.3866/PKU.WHXB202308015
11. [11]
  Xiaochen Zhang , Fei Yu , Jie Ma . Cutting-Edge Applications of Multi-Angle Numerical Simulations for Capacitive Deionization. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-0. doi: 10.3866/PKU.WHXB202311026
12. [12]
  Yuai Duan , Xuanyu Gan , Yao Fu , Yingjie Cao , Hongliang Han , Zhanfang Ma . Application and Innovative Design of Digital Technology in the Preparation Experiment of Cis(Trans)-Diglycine Copper Complexes. University Chemistry, 2026, 41(1): 373-381. doi: 10.12461/PKU.DXHX202504048
13. [13]
  Chenxu Gong , Weizhen Wang , Ruiying Zhang , Wenfeng Wang , Yuanming Li , Yaofeng Yuan , Keyin Ye . Computational Chemistry-Assisted Organic Structure Analysis (CCAOSA): A Case Study of Propeller-Shaped Hexabenzotriphenylene. University Chemistry, 2026, 41(4): 438-446. doi: 10.12461/PKU.DXHX202503076
14. [14]
  Shuangshuang Mao , Juhua Luo , Bingjie Han , Jiahuan Shi , Yujia Gu . Covalent organic framework-derived Fe₃C/NC/TiO₂ heterostructures for high-performance electromagnetic wave absorption. Acta Physico-Chimica Sinica, 2026, 42(7): 100290-. doi: 10.1016/j.actphy.2026.100290
15. [15]
  Hao Wu , Fengqi Li , Xinwei Shi , Haifeng Bian , Qing Zhou , Shunshun Jia , Yujie Ma , Jian Gu , Jingzi Zhang , Shuijian He , Xiangkang Meng . Machine-learning guides discovery of multi-principal element alloys as electrocatalyst for hydrogen evolution reaction. Acta Physico-Chimica Sinica, 2026, 42(8): 100227-0. doi: 10.1016/j.actphy.2025.100227
16. [16]
  Yang Wang , Shuangliang Liu , Jianbo Zhao . Exploring the mechanism of Diels-Alder reaction: a computational chemistry experiment for undergraduate students. University Chemistry, 2026, 41(7): 257-265. doi: 10.12461/PKU.DXHX202504061
17. [17]
  Hongfei Yin , Mengling Hong , Jinyang Zhang , Wentao Wang , Wei Chen , Guozhi Wu . 氧空位介导的2D/2D Bi₂MoO₆/Bi₂O₂S S型异质结用于高效CO₂光还原. Acta Physico-Chimica Sinica, 2026, 42(9): 100332-. doi: 10.1016/j.actphy.2026.100332
18. [18]
  Meifeng Zhu , Jin Cheng , Kai Huang , Cheng Lian , Shouhong Xu , Honglai Liu . Classical Density Functional Theory for Understanding Electrochemical Interface. University Chemistry, 2025, 40(3): 148-152. doi: 10.12461/PKU.DXHX202405166
19. [19]
  Yupeng TANG , Haiying YANG , Fan JIN , Nan LI . Hydrogen storage properties of C₆S₆Li₆: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1827-1839. doi: 10.11862/CJIC.20240460
20. [20]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1067)
HTML views(106)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142