Citation: S. Narayanan, J. Judith Vijaya, S. Sivasanker, Sihai Yang, L. John Kennedy. Hierarchical ZSM-5 catalyst synthesized by a Triton X-100 assisted hydrothermal method[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1892-1989. doi: 10.1016/S1872-2067(14)60177-7 shu

Hierarchical ZSM-5 catalyst synthesized by a Triton X-100 assisted hydrothermal method

1.
a Catalysis & Nanomaterials Research Laboratory, Department of Chemistry, Loyola College (Autonomous), Chennai 600 034, India;

Corresponding author: J. Judith Vijaya,
Received Date: 11 April 2014
Available Online: 17 June 2014

ZSM-5 zeolite with a hexagonal cubic morphology was synthesized by a hydrothermal method using Triton X-100, a nonionic surfactant. The samples prepared with and without the surfactant were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy, N₂ adsorption, high resolution transmission electron microscopy (TEM), high resolution scanning electron microscopy, energy dispersive X-ray analysis, and NH₃ temperature-programmed desorption. The XRD patterns confirmed the formation of a pure ZSM-5 crystalline phase without secondary phases. TEM images revealed that the hexagonal cubes were made of peanut-shaped nanoparticles with voids. The catalytic activity of the zeolite samples was evaluated using the selective oxidation of benzyl alcohol with tertiary-butyl hydrogen peroxide as the oxidant at 90 ℃. The surfactant-assisted preparation yielded a zeolite that gave a higher conversion than the one prepared in the absence of the surfactant. The catalyst was retrieved and reused four times without significant loss in activity and selectivity.
- Heterogeneous catalysis,
- ZSM-5 zeolite,
- Hydrothermal synthesis,
- Selective oxidation,
- Surfactant,
- Triton X-100
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沈阳化工大学材料科学与工程学院沈阳 110142