Citation: Pengjia Tan, Zhihua Gao, Chaofeng Shen, Yali Du, Xiaodong Li, Wei Huang. Ni-Mg-Al solid basic layered double oxide catalysts prepared using surfactant-assisted coprecipitation method for CO₂ reforming of CH₄[J]. Chinese Journal of Catalysis, ;2014, 35(12): 1955-1971. doi: 10.1016/S1872-2067(14)60171-6 shu

Ni-Mg-Al solid basic layered double oxide catalysts prepared using surfactant-assisted coprecipitation method for CO₂ reforming of CH₄

Pengjia Tan ^a,b ,
Zhihua Gao ^a,, ,
Chaofeng Shen ^c ,
Yali Du ^a ,
Xiaodong Li ^a ,
Wei Huang ^a,,

1.
a. Key Laboratory of Coal Science and Technology, Ministry of Education of China and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China;

Corresponding author: Zhihua Gao, Wei Huang,
Received Date: 27 April 2014
Available Online: 1 July 2014
Fund Project: 国家高技术研究发展计划(863计划, 2013AA051201). (863计划, 2013AA051201)

Ni-Mg-Al solid basic catalysts for CO₂ reforming of CH₄ were prepared using a surfactant-assisted coprecipitation method. The preferred orientations of the surfactants on the Ni(111) and Ni(200) crystal planes were investigated. The catalytic performance of the surfactant-modified catalysts was tested at 800 ℃. The cetyltrimethylammonium bromide (CTAB)-modified catalyst (CB-LDO; LDO = layered double oxide) was further studied at various reaction temperatures. All the catalysts were characterized using Fourier-transform infrared spectroscopy, X-ray diffraction, temperature- programmed reduction, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy, and temperature-programmed oxidation. The results show that growth of the Ni(200) plane is promoted by tetrapropylammonium hydroxide and restrained by P123, PVP, and CTAB. The crystallinity degree of Ni(200) plays a key role in the activation of CH₄. The CB-LDO catalysts retain high activities and stabilities, because of the crystal phase transformation at high temperature during the reaction; this leads to the formation of spinel NiAl₂O₄ and exposure of the Ni(200) crystal plane.
- Surfactant,
- Coprecipitation method,
- Nickel,
- Magnesium aluminum oxide,
- Methane,
- Carbon dioxide,
- Reforming
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沈阳化工大学材料科学与工程学院沈阳 110142

Ni-Mg-Al solid basic layered double oxide catalysts prepared using surfactant-assisted coprecipitation method for CO2 reforming of CH4

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Ni-Mg-Al solid basic layered double oxide catalysts prepared using surfactant-assisted coprecipitation method for CO₂ reforming of CH₄